Am]Mn(H2 POO)3 : A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand

Journal of the American Chemical Society
Yue WuAnthony K Cheetham

Abstract

A family of five hybrid ABX3 perovskites has been synthesized using hypophosphite (H2POO)- as the X-site ion. These compounds adopt the general formula [Am]Mn(H2POO)3, where Am = guanidinium (GUA), formamidinium (FA), imidazolium, triazolium, and dabconium. We explore the diverse structural and phase transition behavior of these materials through single-crystal diffraction measurements and demonstrate contrasting magnetism in two of the phases, Am = GUA and FA, that arises from structural distortions. The results show that hypophosphite perovskites offer a promising platform for generating new functional materials.

References

Mar 16, 2004·Acta Crystallographica. Section B, Structural Science·Christopher J Howard, Zhaoming Zhang
Jul 16, 2008·Journal of Computational Chemistry·Jürgen Hafner
Jul 19, 2008·Journal of the American Chemical Society·Prashant JainAnthony K Cheetham
Jul 7, 2009·Acta Crystallographica. Section C, Crystal Structure Communications·Hind A MaouelEric Le Fur
Aug 18, 2010·Angewandte Chemie·Wen ZhangKunio Awaga
Aug 30, 2011·Journal of the American Chemical Society·Guan-Cheng XuSong Gao
Jun 8, 2013·Acta Crystallographica. Section C, Crystal Structure Communications·Bi-Qin WangZhi Zhang
Dec 11, 2014·Nature Communications·Pascal SchouwinkRadovan Černý
Mar 15, 2015·Chemical Communications : Chem Comm·Jung-Hoon LeeAnthony K Cheetham
Sep 10, 2015·Chemical Communications : Chem Comm·Gregor KieslichAnthony K Cheetham
Apr 5, 2016·Chemical Reviews·Bayrammurad Saparov, David B Mitzi
Apr 9, 2016·Journal of the American Chemical Society·Joshua A HillAndrew L Goodwin
Aug 18, 2016·Journal of the American Chemical Society·Samuel G DuykerAndrew L Goodwin
Nov 15, 2016·Physical Chemistry Chemical Physics : PCCP·Hanna L B BoströmAndrew L Goodwin
Jun 1, 2015·Chemical Science·Gregor KieslichAnthony K Cheetham

❮ Previous
Next ❯

Citations

Mar 29, 2018·Chemical Communications : Chem Comm·Yue WuAnthony K Cheetham
Jun 20, 2018·Chemistry : a European Journal·Yue WuAnthony K Cheetham
Dec 18, 2018·Chemical Society Reviews·Xinyuan ZhangJunhua Luo
Dec 21, 2018·Advanced Materials·Julian Gebhardt, Andrew M Rappe
Feb 20, 2019·Chemical Communications : Chem Comm·Hayden A EvansAnthony K Cheetham
May 1, 2019·Chemistry, an Asian Journal·Yu PengJunhua Luo
May 29, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Mirosław MączkaWaldeci Paraguassu
Nov 2, 2019·Angewandte Chemie·Chao ShiHeng-Yun Ye
Aug 5, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Stefan BurgerGregor Kieslich
Jun 20, 2018·Nature Communications·Hanna L B BoströmAndrew L Goodwin
Feb 2, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Mirosław MączkaAdam Sieradzki
Feb 16, 2021·Chemical Communications : Chem Comm·Xiaolong HeYongbing Tang
Nov 14, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Aneta Ciupa-LitwaMirosław Mączka
May 12, 2021·Nature Chemistry·Bikash Kumar ShawThomas D Bennett
Apr 2, 2020·Journal of the American Chemical Society·Bin-Bin DengWei-Qiang Liao

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Dalton Transactions : an International Journal of Inorganic Chemistry
J Paul AttfieldRussell E Morris
© 2022 Meta ULC. All rights reserved