An arch-bridge-type fluorophore for bridging the gap between aggregation-caused quenching (ACQ) and aggregation-induced emission (AIE)

Chemical Science
Manna HuangYiqian Wan

Abstract

Solution and solid dual photoluminescence (PL) molecules fill the substantial gap between ACQ and AIE molecules to explore the mechanism of molecular luminescence in greater detail and to facilitate practical applications. A unique arch-bridge-like thiazolo[5,4-b]thieno[3,2-e]pyridine moiety is obtained as a stator after the rigidification of rotor 1 by intramolecular H-bonding of ortho -OH or -NH2 to afford two classes of solid and solution dual PL molecules. As a typical example, DF5 is dual PL active. Moreover, the large Stokes shift with high dual PL efficiency (ΦF up to 51% in the solid state, 80% in DMF, 74% in DMSO, and 100% in water), together with the good thermal stability (Tm > 200 °C and T05 > 200 °C), make it more practical for promising optoelectronic and biological applications.

References

Sep 21, 2002·Chemical Communications : Chem Comm·J LuoB Z Tang
Mar 15, 2005·Inorganic Chemistry·Henry J TracyKimberly Watts
Oct 1, 1980·Proceedings of the National Academy of Sciences of the United States of America·S Scheiner, V M Kolb
Aug 5, 1994·Science·S A Jenekhe, J A Osaheni
Jul 15, 2009·Chemical Communications : Chem Comm·Yuning HongBen Zhong Tang
Jul 13, 2011·The Journal of Chemical Physics·Chunmei DengBen Zhong Tang
Jul 30, 2011·Chemical Society Reviews·Yuning HongBen Zhong Tang
May 15, 2012·Accounts of Chemical Research·Liang-Qiu LuWen-Jing Xiao
Jun 8, 2013·Accounts of Chemical Research·Dan DingBen Zhong Tang
Aug 15, 2013·Chemical Society Reviews·Sebastian van de Linde, Markus Sauer
Nov 5, 2013·Chemical Communications : Chem Comm·Andrei Y BochkovValery F Traven
Mar 13, 2014·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Keitaro UmezawaKoji Suzuki
Apr 16, 2014·Chemical Society Reviews·Rongrong HuBen Zhong Tang
Jun 24, 2014·Journal of the American Chemical Society·Jiun-Jie ShieChi-Huey Wong
Sep 11, 2014·Physical Chemistry Chemical Physics : PCCP·Tsutomu ShiragamiMasahide Yasuda
Oct 11, 2014·Chemistry : a European Journal·Nelson L C LeungBen Zhong Tang
Nov 7, 2014·Chemical Society Reviews·Ryan T K KwokBen Zhong Tang
Nov 27, 2014·Chemical Communications : Chem Comm·Xiaoqing WangZhipeng Liu
Dec 5, 2014·Chemical Society Reviews·Xiao-Peng HeGuo-Rong Chen
Dec 24, 2014·Journal of the American Chemical Society·Yusuke OkazawaMichito Yoshizawa
Jan 27, 2015·Chemical Communications : Chem Comm·Cangjie YangMingfeng Wang
Mar 3, 2015·Angewandte Chemie·Hirofumi NaitoYoshiki Chujo
Mar 21, 2015·Scientific Reports·Yan ZhangJian-Guo Deng
Jun 20, 2015·Angewandte Chemie·Chun ZhangHui-Bi Xu
Jul 21, 2015·Langmuir : the ACS Journal of Surfaces and Colloids·Daniel López, Eva M García-Frutos
Aug 20, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Christian Reus, Thomas Baumgartner
Oct 20, 2015·Nanoscale·Lulin YanWenjing Tian
Oct 23, 2015·Chemical Reviews·Ju MeiBen Zhong Tang
Oct 1, 2015·Chemical Science·Zujin ZhaoBen Zhong Tang

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Citations

Feb 6, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yunxi YeJinlou Gu
Jan 30, 2020·Biomaterials Science·Haifeng Fan, Zhiguang Guo
Jan 31, 2020·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Prabhat MajumdarShinto Varghese
Apr 17, 2020·Wiley Interdisciplinary Reviews. Nanomedicine and Nanobiotechnology·Dazhuang XuGang Liu
Sep 30, 2016·Chemistry : a European Journal·George Rajendra KumarPakkirisamy Thilagar
Aug 1, 2020·Advanced Materials·Haoke ZhangBen Zhong Tang
Dec 8, 2017·Organic & Biomolecular Chemistry·Jingwei WangQidan Ling
Jul 18, 2018·Chemistry : a European Journal·Yunxiang LeiYuping Dong
Aug 15, 2017·BioTechniques·Alexey A PakhomovVladimir I Martynov
Jul 21, 2018·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Lei ShiXiao-Qi Yu
Dec 29, 2020·Chemistry : a European Journal·Valmik P JejurkarSatyajit Saha
Aug 14, 2020·Journal of the American Chemical Society·Zi YaoJennifer A Prescher
Jun 12, 2021·Analytical Chemistry·Wan FangYu Fang
Jun 23, 2021·Chemistry, an Asian Journal·Steffen RiebeJens Voskuhl
Feb 23, 2018·ACS Applied Materials & Interfaces·Soochan LeeWonyoung Choe

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Methods Mentioned

BETA
biosensors
differential scanning calorimetry

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