An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference

Organic & Biomolecular Chemistry
László NyulásziRégis Réau

Abstract

The low aromaticity of phosphole can be switched to low antiaromaticity by oxidizing the phosphorus atom. This subtle change in the mode of delocalisation alters substantially the chemical behaviour of these heteroles.

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Citations

Jun 14, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Rózsa SzűcsMuriel Hissler
Jul 7, 2007·Chemistry : a European Journal·Tomohiro AgouTakayuki Kawashima
Oct 11, 2008·Chemistry : a European Journal·Yvonne DienesThomas Baumgartner
Dec 4, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Jeanne Crassous, Régis Réau
Aug 18, 2010·Chemistry : a European Journal·Omrane FadhelRégis Réau
Apr 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Di WuFrançois Mathey
Mar 27, 2009·Chemical Communications : Chem Comm·Dirk SchmidLászló Nyulászi
Jun 4, 2014·Chemistry : a European Journal·Elisabet ÖbergSascha Ott
Apr 30, 2019·Chemistry : a European Journal·Olatz LarrañagaAbel de Cózar
Mar 15, 2011·Organic & Biomolecular Chemistry·Oldamur Hollóczki, László Nyulászi
Sep 5, 2012·Chemistry, an Asian Journal·David HanifiYi Liu
Feb 6, 2020·Chemical Communications : Chem Comm·Nabila Rauf NazRainer Streubel
Jul 2, 2015·Chemistry : a European Journal·Dominique MieselHeinrich Lang
Apr 14, 2010·Chemical Reviews·L Kollár, G Keglevich
Nov 10, 2006·Chemical Reviews·Thomas Baumgartner, Régis Réau
May 22, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu ZhaoJun Zhu
Mar 8, 2019·Journal of the American Chemical Society·Hiroto OmoriHiroshi Shinokubo

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