An endohedral single-molecule magnet with long relaxation times: DySc2N@C80

Journal of the American Chemical Society
Rasmus WesterströmThomas Greber

Abstract

The magnetism of DySc(2)N@C(80) endofullerene was studied with X-ray magnetic circular dichroism (XMCD) and a magnetometer with a superconducting quantum interference device (SQUID) down to temperatures of 2 K and in fields up to 7 T. XMCD shows hysteresis of the 4f spin and orbital moment in Dy(III) ions. SQUID magnetometry indicates hysteresis below 6 K, while thermal and nonthermal relaxation is observed. Dilution of DySc(2)N@C(80) samples with C(60) increases the zero-field 4f electron relaxation time at 2 K to several hours.

References

Jun 1, 1991·Physical Review. B, Condensed Matter· van der Laan G, B T Thole
Mar 23, 1992·Physical Review Letters·B T Thole van der Laan G
Feb 1, 1993·Physical Review Letters·P CarraX Wang
May 13, 1996·Physical Review Letters·J R FriedmanR Ziolo
Apr 12, 2001·Nature·M N Leuenberger, D Loss
Jul 17, 2003·Journal of the American Chemical Society·Naoto IshikawaYoukoh Kaizu
Mar 18, 2005·Journal of the American Chemical Society·Naoto IshikawaWolfgang Wernsdorfer
Feb 8, 2006·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Helen F Gleeson, Linda S Hirst
Apr 8, 2006·The Journal of Physical Chemistry. B·F BondinoA Goldoni
Jul 11, 2006·The Journal of Physical Chemistry. B·Ning ChenChun-Ru Wang
Jul 7, 2007·Physical Chemistry Chemical Physics : PCCP·Lothar Dunsch, Shangfeng Yang
Jul 28, 2007·Small·Lothar Dunsch, Shangfeng Yang
Nov 17, 2007·The Journal of Physical Chemistry. B·Shangfeng YangLothar Dunsch
Feb 26, 2008·Nature Materials·Lapo Bogani, Wolfgang Wernsdorfer
Jun 19, 2008·Journal of the American Chemical Society·Murad A AldamenAlejandro Gaita-Ariño
Jun 21, 2008·Chemical Communications : Chem Comm·Shangfeng YangLothar Dunsch
Aug 20, 2009·Journal of the American Chemical Society·Jeffrey D Rinehart, Jeffrey R Long
Sep 25, 2009·Angewandte Chemie·Manuel N ChaurLuis Echegoyen
Jan 9, 2010·Journal of the American Chemical Society·Danna E FreedmanJeffrey R Long
Aug 31, 2010·Angewandte Chemie·Shang-Da JiangSong Gao
Feb 11, 2011·Angewandte Chemie·Nicola MagnaniRoberto Caciuffo
Mar 16, 2011·Journal of the American Chemical Society·Shang-Da JiangSong Gao
Mar 24, 2011·Journal of the American Chemical Society·Jérôme LongMuralee Murugesu
May 14, 2011·Journal of the American Chemical Society·Fatemah HabibMuralee Murugesu
May 28, 2011·Chemistry : a European Journal·Akiko WatanabeTakashi Kajiwara
Sep 16, 2011·Inorganic Chemistry·Maria A AntunesManuel Almeida
Oct 29, 2011·Journal of the American Chemical Society·Matthew JeleticMuralee Murugesu
Dec 7, 2011·Journal of the American Chemical Society·Joseph M Zadrozny, Jeffrey R Long
Feb 24, 2012·Inorganic Chemistry·Shang-Da JiangSong Gao

❮ Previous
Next ❯

Citations

May 3, 2013·Chemical Reviews·Alexey A PopovLothar Dunsch
Aug 11, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Christian Aa ThuesenJesper Bendix
Feb 18, 2016·Journal of the American Chemical Society·Yan-Cong ChenMing-Liang Tong
Aug 11, 2016·Inorganic Chemistry·Liviu Ungur, Liviu F Chibotaru
Nov 1, 2016·Journal of the American Chemical Society·Fupin LiuShangfeng Yang
Nov 2, 2016·Nano Letters·Romana BalticHarald Brune
Jan 31, 2017·Chemistry : a European Journal·Yan-Cong ChenMing-Liang Tong
Mar 10, 2017·Nature·Fabian D NattererChristopher P Lutz
Dec 24, 2016·Journal of Synchrotron Radiation·Matthias MuntwilerThomas Greber
Jul 1, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yongjian LiChunru Wang
Jul 7, 2017·Chemical Society Reviews·Shangfeng YangFei Jin
Mar 2, 2018·Chemical Society Reviews·Jun-Liang LiuMing-Liang Tong
Nov 26, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Yongjian LiChunru Wang
Sep 9, 2017·Nanotechnology·Fabian FritzCarola Meyer
Feb 3, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Peng ZhangJinkui Tang
Feb 1, 2018·Chemistry : a European Journal·Min Feng, Ming-Liang Tong
Aug 29, 2014·Chemistry : a European Journal·Jan DreiserThomas Greber
Nov 18, 2014·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Zhuxia ZhangBingshe Xu
Aug 23, 2018·Nanoscale·Stanislav M AvdoshenkoRasmus Westerström
Aug 7, 2018·Chemical Communications : Chem Comm·Christin SchlesierAlexey A Popov
Feb 14, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Lukas Spree, Alexey A Popov
May 28, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Xuan WangEn-Qing Gao
Jul 18, 2019·Chemical Communications : Chem Comm·Bing-Cheng LiuYan-Zhen Zheng
Jul 8, 2017·Beilstein Journal of Nanotechnology·Sebastian SchimmelChristian Hess
Nov 15, 2016·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Wolfgang Kuch, Matthias Bernien
Aug 18, 2020·Chemical Communications : Chem Comm·Mingzhe NieTaishan Wang
Apr 22, 2015·Journal of Physics. Condensed Matter : an Institute of Physics Journal·J Dreiser
Jun 12, 2013·Chemistry : a European Journal·Min RenLi-Min Zheng

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.