An insight into the process and mechanism of a mechanically activated reaction for synthesizing AlH3 nano-composites

Dalton Transactions : an International Journal of Inorganic Chemistry
Congwen DuanHuan Yu

Abstract

The reaction pathway as well as the mechanism of the solid state reaction between MgH2 and AlCl3 has been a mystery so far. Based on SEM, TEM and NMR (Nuclear Magnetic Resonance) analyses, an amorphous intermediate (AlH6)n was preferentially formed and recrystallized as a γ phase at the final stage of the reaction. As a novel finding, this research provides a deep insight into the process and mechanism of this mechanically activated reaction.

References

Mar 11, 2004·Chemical Reviews·Wojciech Grochala, Peter P Edwards
Jul 21, 2006·The Journal of Physical Chemistry. B·Jason Graetz, James J Reilly
Dec 22, 2006·The Journal of Physical Chemistry. B·Hendrik W BrinksBjørn C Hauback
Feb 13, 2007·Inorganic Chemistry·Volodymyr A YartysHermann Emerich
Apr 19, 2007·Journal of the American Chemical Society·A GrubisicH Schnöckel
Sep 13, 2007·Chemical Reviews·Shin-Ichi OrimoCraig M Jensen
May 8, 2008·Journal of the American Chemical Society·Cornelis P BaldéKrijn P de Jong
Dec 18, 2008·Chemical Society Reviews·Jason Graetz
Apr 9, 2015·Chemical Communications : Chem Comm·Kui ZhangXiaoqing Pan

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