An unusual chemoselective oxidation strategy by an unprecedented exploration of an electrophilic center of DMSO: a new facet to classical DMSO oxidation

Chemical Communications : Chem Comm
Rajesh CheboluP C Ravikumar

Abstract

A conceptually new dimethyl sulfoxide (DMSO) based oxidation process without the use of any activator has been demonstrated for the oxidation of active methylenes and benzhydrols. The developed protocol utilizes the electrophilic center of DMSO for oxidation, which was unexplored before. Mechanistic investigation has confirmed that the source of oxygen is DMSO.

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Citations

Oct 8, 2016·Organic & Biomolecular Chemistry·Simmi SharmaBhahwal Ali Shah
Mar 21, 2017·Organic & Biomolecular Chemistry·Hasan MtiraouiCyrille Sabot
Aug 7, 2017·New Journal of Chemistry = Nouveau Journal De Chimie·A MalekafzaliF W Patureau
Apr 15, 2021·The Journal of Organic Chemistry·Shiv ChandKrishna Nand Singh

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