PMID: 9558713Apr 29, 1998Paper

An unusual dienone-phenol rearrangement product formed during the synthesis of mometasone furoate (Sch 32088)

Steroids
R W DraperA T McPhail

Abstract

The structure of an unusual dienone-phenol rearrangement product 4 obtained during the synthesis of mometasone furoate (Sch 32088) was assigned on the basis of NMR and x-ray crystallographic data. The mechanism of formation is discussed.

References

Sep 1, 1987·Journal of Medicinal Chemistry·E L ShapiroA S Watnick
Jan 1, 1987·Journal of Steroid Biochemistry·T L PopperE L Shapiro

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Citations

Jun 6, 2003·International Journal of Pharmaceutics·Xiao Wei TengNeal M Davies
Oct 4, 2011·Journal of Natural Products·Maria Conceição M TorresMarcos Hikari Toyama
Oct 19, 2001·Chemical & Pharmaceutical Bulletin·M I Choudhary Atta-ur-Rahman
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Nov 13, 2004·The Journal of Chemical Physics·Stephen W WattSam Motherwell
Jan 1, 2008·Acta Crystallographica. Section E, Structure Reports Online·Vincent O Nyamori, Muhammad D Bala
Jul 10, 2013·European Journal of Medicinal Chemistry·Eduard BadarauMartin Griffin
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Jun 15, 2011·Journal of Molecular Modeling·Tihomir TomašićLucija Peterlin Mašič
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Apr 7, 2011·Inorganic Chemistry·Łukasz ŁapokSergiu M Gorun

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