Anion-induced 3d-4f luminescent coordination clusters: structural characteristics and chemical fixation of CO2 under mild conditions

Dalton Transactions : an International Journal of Inorganic Chemistry
Ruilian ZhangWeisheng Liu

Abstract

Two series of anion-induced 3d-4f luminescent clusters ZnII2LnIII2L4 (LnIII = Eu3+, Tb3+, Er3+, Yb3+, Nd3+) and ZnII4LnIII2L4 (LnIII = Tb3+, Nd3+) based on μ3-OH group were synthesized and characterized. The difference in anions not only leads to significant structural changes, but also changes the luminescent properties of the 3d-4f coordination clusters. These complexes show excellent catalytic performance for CO2 conversion to obtain cyclic carbonates with wide substrate scopes and high selectivity under mild conditions. Turnover numbers were up to 9000, and turnover frequencies obtained were 660 h-1. The ligand is simple and the complexes are easily obtained even on a large scale. Moreover, these complexes also feature lanthanide-characterized luminescence both in visible and near infrared regions with relatively long luminescence lifetimes and high quantum yields, suggesting promising multifunctional applications.

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Citations

Jul 28, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Kieran Griffiths, George E Kostakis
Nov 30, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Prashant KumarGeorge E Kostakis
Nov 25, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Uwe Bayer, Reiner Anwander
Jan 14, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Kuan YinYingming Yao

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Methods Mentioned

BETA
X-ray
single
1
H
NMR

Software Mentioned

SADABS
Olex2

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