Anionic tethered N-heterocyclic carbene chemistry

Chemical Society Reviews
Stephen T LiddlePolly L Arnold

Abstract

Since the discovery of a stable "bottleable" N-heterocyclic carbene (NHC), there has been a spectacular explosion of interest in this ligand class. This interest stems from a desire to understand the fundamentals of the structure and bonding of these systems, but also because of their numerous and emerging applications in small molecule activation, homogeneous catalysis and Lewis acid-catalysed reactions. In this Tutorial Review, we introduce the reader to NHCs, cover general synthetic methods to prepare anionic tethered NHCs and their metal complexes, and discuss emerging applications in reactivity and catalytic studies.

References

Dec 26, 2001·Chemical Reviews·Didier BourissouGuy Bertrand
Sep 21, 2002·Chemical Communications : Chem Comm·P L ArnoldC Wilson
Sep 19, 2003·Chemical Communications : Chem Comm·Hidenori AiharaHiroyuki Kawaguchi
Oct 9, 2003·Journal of the American Chemical Society·Joshua J Van VeldhuizenAmir H Hoveyda
Mar 11, 2004·Chemical Communications : Chem Comm·Richard E DouthwaiteBenson M Kariuki
Nov 30, 2004·Chemical Communications : Chem Comm·Shaheed A MungurPolly L Arnold
Nov 18, 2005·Chemical Communications : Chem Comm·Polly L Arnold, Stephen T Liddle
Nov 18, 2005·Chemical Communications : Chem Comm·Benjamin E KetzRobert M Waymouth
Mar 4, 2006·Chemical Communications : Chem Comm·Dipti PatelPolly L Arnold
Sep 28, 2006·Chemical Communications : Chem Comm·Polly L Arnold, Stephen T Liddle
Mar 28, 2007·Chemical Society Reviews·Olaf Kühl
Apr 15, 2002·Angewandte Chemie·Wolfgang A Herrmann

❮ Previous
Next ❯

Citations

Jul 26, 2011·Inorganic Chemistry·Rajendra S GhadwalHerbert W Roesky
Jul 9, 2010·Journal of the American Chemical Society·Rajendra S GhadwalDietmar Stalke
Mar 31, 2011·Journal of the American Chemical Society·Wen-Xiong ZhangZhaomin Hou
Jun 7, 2011·Journal of the American Chemical Society·Janeth NavarroEduardo Sola
Aug 16, 2012·Journal of the American Chemical Society·Zachary M HudsonSuning Wang
Apr 3, 2009·Journal of the American Chemical Society·Kelly E KrahulicRoland Roesler
Sep 13, 2011·Organic Letters·Johnathon T Hutt, Zachary D Aron
Oct 15, 2009·Chemical Communications : Chem Comm·Tieqiang ZengChao-Jun Li
Dec 22, 2009·Chemical Communications : Chem Comm·Masaki OkamotoSatoshi Sakaguchi
Aug 24, 2010·Chemical Communications : Chem Comm·Marc R L Furst, Catherine S J Cazin
Aug 25, 2010·Chemical Communications : Chem Comm·Christine Hawner, Alexandre Alexakis
Jan 1, 2008·Acta Crystallographica. Section E, Structure Reports Online·Chuang ZhouMei-Ming Luo
Oct 1, 2009·Chemistry, an Asian Journal·Akkattu T BijuFrank Glorius
Oct 9, 2015·Inorganic Chemistry·Sara FuertesVioleta Sicilia
Jan 24, 2015·The Journal of Organic Chemistry·Viktor O IaroshenkoPeter Langer
Jun 16, 2016·Journal of the American Chemical Society·Jiaxiang ChuGuy Bertrand
Jun 11, 2011·Journal of the American Chemical Society·Polly L ArnoldRobert P Tooze
Jun 3, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Rajendra S GhadwalSerhiy Demeshko
Nov 25, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Fady NahraCatherine S J Cazin
Jan 14, 2017·Chemical Society Reviews·Sophie HameuryPierre Braunstein
Jan 28, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Sean W ReillyHenry U Valle
Jan 14, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Marta Roselló-Merino, Stephen M Mansell
Oct 22, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Andrea CingolaniRita Mazzoni
Jul 22, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jordan HolmesCharlotte E Willans
Jun 13, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Polly L ArnoldJason B Love
Mar 1, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Taotao LuZi-Ling Xue
Jun 22, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Julie HessevikErwan Le Roux
Nov 1, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Bor-Hunn HuangBao-Tsan Ko
Jun 9, 2015·Chemical Communications : Chem Comm·Fabian CarsonBelén Martín-Matute
Jan 23, 2015·Chemical Society Reviews·Dao Zhang, Guofu Zi
Jul 13, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Qiuming LiangDatong Song
May 7, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Matthieu RaynalPierre Braunstein

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.