Anti-Markovnikov hydroarylation of styrenes catalyzed by an in situ generated ruthenium complex

Chemical Communications : Chem Comm
Rémi MartinezSylvain Darses

Abstract

An efficient and practical catalytic system for the anti-Markovnikov ruthenium-catalyzed hydroarylation of styrenes with acetophenone, allowing a straightforward access to bibenzyl backbones, is described for the first time: this process, involving regioselective C-H bond activation, is complementary to a Friedel-Crafts type reaction giving the branched adduct.

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Citations

Sep 1, 2012·Chemical Reviews·Percia Beatrice ArockiamPierre H Dixneuf
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