PMID: 11918029Mar 29, 2002Paper

Arsenic(III) oxidation and arsenic(V) adsorption reactions on synthetic birnessite

Environmental Science & Technology
Bruce A ManningDonald L Suarez

Abstract

The oxidation of arsenite (As(III)) by manganese oxide is an important reaction in both the natural cycling of As and the development of remediation technology for lowering the concentration of dissolved As(III) in drinking water. This study used both a conventional stirred reaction apparatus and extended X-ray absorption fine structure (EXAFS) spectroscopy to investigate the reactions of As(III) and As(V) with synthetic birnessite (MnO2). Stirred reactor experiments indicate that As(III) is oxidized by MnO2 followed by the adsorption of the As(V) reaction product on the MnO2 solid phase. The As(V)-Mn interatomic distance determined by EXAFS analysis for both As(III)- and As(V)-treated MnO2 was 3.22 A, giving evidence for the formation of As(V) adsorption complexes on MnO2 crystallite surfaces. The most likely As(V)-MnO2 complex is a bidentate binuclear corner sharing (bridged) complex occurring at MnO2 crystallite edges and interlayer domains. In the As(III)-treated MnO2 systems, reductive dissolution of the MnO2 solid during the oxidation of As(III) caused an increase in the adsorption of As(V) when compared with As(V)-treated MnO2. This suggested that As(III) oxidation caused a surface alteration, creating fresh reaction sit...Continue Reading

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Citations

Jul 24, 2013·Environmental Monitoring and Assessment·Amid P KhodadoustKamel Babaeivelni
May 15, 2004·The Science of the Total Environment·Véronique LenobleJean-Claude Bollinger
Feb 17, 2011·Environmental Science & Technology·Guangliang LiuYong Cai
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May 31, 2012·Environmental Science & Technology·L Camille JonesDonald L Sparks
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