PMID: 28523779DOI: 10.1002/anie.201703155May 20, 2017Paper
Arylative Intramolecular Allylation of Ketones with 1,3-Enynes Enabled by Catalytic Alkenyl-to-Allyl 1,4-Rhodium(I) Migration
Angewandte Chemie
Benjamin M PartridgeHon Wai Lam
Abstract
Alkenyl-to-allyl 1,4-rhodium(I) migration enables the generation of nucleophilic allylrhodium(I) species by remote C-H activation. This new mode of reactivity was employed in the diastereoselective reaction of arylboron reagents with substrates containing a 1,3-enyne tethered to a ketone, to give products containing three contiguous stereocenters. The products can be obtained in high enantioselectivities using a chiral sulfur-alkene ligand.
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Citations
Jan 23, 2018·Chemistry : a European Journal·Johnathon D Dooley, Hon Wai Lam
Oct 6, 2017·Angewandte Chemie·Michael CallinghamHon Wai Lam
Apr 27, 2018·Angewandte Chemie·Jiayu MoLutz Ackermann
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Jul 27, 2017·Angewandte Chemie·Sara CuadrosPaolo Melchiorre
Dec 24, 2018·Chemical Communications : Chem Comm·Rebecca E RuscoeHon Wai Lam
Feb 6, 2020·Chemical Science·Alistair GrovesHon Wai Lam
Dec 24, 2018·Organic Letters·Biao YaoLei Wang
Feb 23, 2019·Organic Letters·Jiaqiong SunXingwei Li
Nov 8, 2019·The Journal of Organic Chemistry·Mohammed Anif PashaDhevalapally B Ramachary
Sep 11, 2020·Journal of the American Chemical Society·Marino BörjessonRuben Martin
Aug 18, 2021·Angewandte Chemie·Takanobu SaitoNobuharu Iwasawa
Nov 19, 2021·Journal of the American Chemical Society·Yuli HeShaolin Zhu
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