Assembling discrete D4R zeolite SBUs through noncovalent interactions. 3. Mediation by butanols and 1,2-bis(dimethylamino)ethane

Inorganic Chemistry
Ramaswamy MurugavelAlexander Steiner

Abstract

The use of tetrameric zinc phosphate [Zn(dipp)(CH(3)OH)](4) (1; dipp = diisopropylphenylphosphate dianion) as a suitable building block for realizing new noncovalently linked extended structures, via facile replacement of coordinated methanol molecules by other alcohols, is reported herein. Compounds [Zn(dipp)(sec-butanol)](4) x 4 H(2)O (2) and [Zn(dipp)(tert-butanol)](4) x 4 H(2)O (3) have been synthesized by the addition of sec- or tert-butanol to 1 at room temperature. The reaction of zinc acetate or zinc sulfate with dippH(2) in the presence of N,N,N',N'-tetramethylethylenediamine (tmeda) under similar reaction conditions results in the formation of [H(2)tmeda][Zn(4)(dipp)(4)(MeOH)(2)(OAc)(2)] x (CH(3)OH) (4) or [H(2)tmeda][Zn(3)(dipp)(3)(dippH)(2)(CH(3)OH)] x (CH(3)OH)(3) (5), respectively. Analytically pure compounds 2-5 have been isolated in the form of single crystals directly from the respective reaction mixtures in very good yields and characterized with the aid of analytical and spectroscopic studies. Single-crystal X-ray diffraction studies reveal that compounds 2 and 3 are neutral tetranuclear zinc phosphates. Compound 4 is also a tetrameric phosphate but is anionic. The core structures of compounds 2-4 resemble th...Continue Reading

References

Oct 26, 2002·Chemical Communications : Chem Comm·Luis A VillaescusaRussell E Morris
Sep 3, 2003·Inorganic Chemistry·Fiona H FryLeone Spiccia
Jul 15, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Ganapathi AnantharamanMathias Noltemeyer
Nov 24, 2004·Inorganic Chemistry·Ramasamy PothirajaRamaswamy Murugavel
Jul 19, 2006·Angewandte Chemie·Ramaswamy MurugavelAlexander Steiner
Oct 3, 2006·Angewandte Chemie·Ramaswamy Murugavel, Subramaniam Kuppuswamy
Mar 16, 2007·Chemical Communications : Chem Comm·Ramaswamy Murugavel, Swaminathan Shanmugan
Sep 12, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Ramaswamy MurugavelMunirathinam Nethaji
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Mar 21, 2008·Chemistry : a European Journal·Ramaswamy Murugavel, Subramaniam Kuppuswamy
Jul 30, 2008·Inorganic Chemistry·Ramaswamy Murugavel, Subramaniam Kuppuswamy
May 8, 2009·Chemistry, an Asian Journal·Ramaswamy MurugavelH C Verma

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Citations

Feb 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Sandeep K GuptaRamaswamy Murugavel
Mar 23, 2018·Chemistry : a European Journal·Ritambhara JangirRamaswamy Murugavel
May 30, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Biswajit SantraAnukul Jana
May 22, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Alok Ch KalitaRamaswamy Murugavel
Nov 11, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Vadapalli ChandrasekharE Carolina Sañudo
Mar 29, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Atanu DeyVadapalli Chandrasekhar
Aug 15, 2014·Inorganic Chemistry·Alok Ch KalitaRamaswamy Murugavel
Mar 13, 2014·Inorganic Chemistry·Alok Ch Kalita, Ramaswamy Murugavel

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