Assembly of a heterobinuclear 2-D network: a rare example of endo- and exocyclic coordination of Pd(II)/Ag(I) in a single macrocycle

Inorganic Chemistry
Il YoonShim Sung Lee

Abstract

The S3O2 macrocycle L1 was synthesized by a dithiol-dihalide coupling reaction under high-dilution conditions. The reaction of L1 with K2PdCl4 afforded an exocoordinated complex 1, [cis-Cl2Pd(L1)], which can then be manipulated to provide a heterobinuclear complex 3, {[Pd(L1)Ag(NO3)(2.5)](NO3)(0.5)}n, utilizing endocyclic Pd(II) and exocyclic Ag(I) in a single macrocycle through a successive reaction with AgNO3. The network of 3 contains a unique honeycomb-like 2-D sheet made up of the repeating unit [Ag6(NO3)6].

References

Mar 23, 2001·Inorganic Chemistry·W HuangQ Meng
Jan 16, 2003·Inorganic Chemistry·H HeJ H Reibenspies
Feb 11, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Yongri JinShim Sung Lee
Jul 5, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Il YoonShim Sung Lee
Nov 8, 2005·Inorganic Chemistry·Daron E JanzenGregory J Grant

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Citations

Nov 26, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiong LiShu-Ling Gong
Sep 27, 2008·Journal of the American Chemical Society·Jai Young LeeShim Sung Lee
Oct 31, 2008·Inorganic Chemistry·Hyun Jee Kim, Shim Sung Lee

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