Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand

Dalton Transactions : an International Journal of Inorganic Chemistry
Yun-Yun ZhengLan-Sun Zheng

Abstract

An undeca-nuclear nickel substituted POM, namely [Ni(H(2)O)(6)][Ni(11)(PW(9)O(34))(2)(IDA)(3)(en)(2)(Hen)(2)(OH)(6)]·(H(2)O)(7)·(H(2)en)(2) (1) (en = 1,2-ethylenediamine, H(2)IDA = iminodiacetic acid), was synthesized through hydrothermal reaction of Na(6)PW(9)O(34), en, H(2)IDA and NiCl(2)·6H(2)O. Single-crystal structure reveals that 1 can be viewed as Ni(6)PW(9) and Ni(5)PW(9) units linked by a μ(3)-O bridge and two IDA(2-) ligands. Magnetic investigation indicates the presence of dominantly ferrimagnetic interactions within the Ni(11) core. Electrochemistry study shows that 1 displays a stable and reproducible voltammetric graph.

References

Jan 22, 2002·Inorganic Chemistry·Ruiyao WangRichard J Staples
May 12, 2005·Angewandte Chemie·Sib Sankar Mal, Ulrich Kortz
Jan 30, 2007·Inorganic Chemistry·Chun-Mei WangGuo-Yu Yang
Feb 26, 2008·Angewandte Chemie·Xiang-Jian KongLan-Sun Zheng
Mar 11, 2008·Inorganic Chemistry·Xiang-Jian KongLan-Sun Zheng
Apr 11, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Céline PichonFrancis Sécheresse
Jan 17, 2009·Journal of the American Chemical Society·Chun-Yan SunZhong-Min Su
May 8, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Chris RitchieLeroy Cronin
Jul 15, 2009·Chemical Communications : Chem Comm·Xiang-Jian KongZhiping Zheng
Dec 1, 2009·Inorganic Chemistry·Hong-Mei ZhangEn-Bo Wang
Feb 5, 2010·Angewandte Chemie·De-Liang LongLeroy Cronin
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Bogdan BotarPaul Kögerler
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Shiwei LinZhiming Zhang
May 21, 2010·Journal of the American Chemical Society·Norberto MasciocchiSilvia Bordiga
Jun 10, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Thomas BoydLeroy Cronin
Aug 20, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Chullikkattil P PradeepLeroy Cronin
Oct 7, 2010·Journal of the American Chemical Society·Shou-Tian ZhengGuo-Yu Yang
Feb 11, 2011·Chemical Communications : Chem Comm·Xikui Fang, Marshall Luban
Apr 19, 2011·Angewandte Chemie·Masooma IbrahimUlrich Kortz
Apr 21, 2011·Angewandte Chemie·Xikui FangMarshall Luban
Jul 14, 2011·Inorganic Chemistry·Guillaume RousseauPierre Mialane

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Citations

Mar 10, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jian-Ping BaiZai-Ming Zhu
Jan 12, 2016·Chemical Communications : Chem Comm·Bassem S BassilUlrich Kortz
Dec 3, 2014·Chemistry : a European Journal·Xin-Xiong LiGuo-Yu Yang

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