Asymmetric Catalytic Reactions of Donor-Acceptor Cyclopropanes.

Angewandte Chemie
Yong XiaXiaoming Feng

Abstract

Due to the synergistic "push-pull" effect of vicinal electron-donating and electron-withdrawing groups, donor-acceptor (D-A) cyclopropanes have been recognized as one of the most powerful building blocks to generate polyfunctional reactive intermediates after a strain-driven ring cleavage. Enantioselective reactions of D-A cyclopropanes provide an efficient approach to enantioenriched acyclic and cyclic compounds. A number of chiral Lewis/Brønsted acids, transition metals, and organocatalysts have been designed for such transformations, including ring-openings, annulations, and rearrangements. This minireview highlights the developments and new advances in this field and describes new synthetic opportunities offered by these interesting methodologies.

References

Apr 21, 2005·Journal of the American Chemical Society·Mukund P SibiCraig P Jasperse
Nov 17, 2005·Journal of the American Chemical Society·Patrick D Pohlhaus, Jeffrey S Johnson
Aug 7, 2009·Angewandte Chemie·Gustav DickmeissKarl Anker Jørgensen
Oct 23, 2009·Chemical Society Reviews·Cheryl A Carson, Michael A Kerr
Apr 16, 2011·Accounts of Chemical Research·Dan ZhangYong Qin
Jun 28, 2011·Accounts of Chemical Research·XiaoHua LiuXiaoMing Feng
Oct 27, 2011·Journal of the American Chemical Society·Joseph MoranMichael J Krische
Nov 25, 2011·Chemistry : a European Journal·Filippo De SimoneJérôme Waser
Oct 4, 2012·Journal of the American Chemical Society·Barry M TrostSimon J Sprague
May 9, 2013·Journal of the American Chemical Society·Hu XiongYong Tang
Oct 1, 2013·Chemical Communications : Chem Comm·Rubén TejeroJuan C Carretero
Nov 22, 2013·Chemical Society Reviews·Marchello A CavittStefan France
Apr 16, 2014·Journal of the American Chemical Society·Florian de NanteuilJerome Waser
Apr 29, 2014·Angewandte Chemie·Tobias F SchneiderDaniel B Werz
Jun 28, 2014·Chemical Communications : Chem Comm·F de NanteuilJ Waser
Jul 24, 2014·Nature Chemistry·Takuya HashimotoKeiji Maruoka
Nov 27, 2014·Organic & Biomolecular Chemistry·Huck K GroverMichael A Kerr
Jan 13, 2015·Journal of the American Chemical Society·Kim Søholm HalskovKarl Anker Jørgensen
Jun 13, 2015·Journal of the American Chemical Society·Hao XuYong Tang
Nov 6, 2015·Journal of the American Chemical Society·Qi-Kai KangYong Tang
Mar 26, 2016·Journal of the American Chemical Society·Adrian G AmadorTehshik P Yoon
May 26, 2016·Organic & Biomolecular Chemistry·Xuan FuXiaoming Feng
Oct 30, 2016·Angewandte Chemie·Dong-Chao WangShu-Li You
Oct 3, 2017·Accounts of Chemical Research·Xiaohua LiuXiaoming Feng

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Citations

Oct 13, 2020·Chemical Communications : Chem Comm·Fenzhen ChangXiaoming Feng
Mar 5, 2021·Accounts of Chemical Research·André U Augustin, Daniel B Werz
May 7, 2021·Chemical Communications : Chem Comm·Ji-Wei SangHai-Ming Guo
Jun 12, 2021·Organic & Biomolecular Chemistry·Julien Caillé, Raphaël Robiette
Jul 15, 2021·Chemical Science·Vincent PirenneJerome Waser
Aug 19, 2021·Journal of the American Chemical Society·Anna E VartanovaIgor V Alabugin

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