B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines

Dalton Transactions : an International Journal of Inorganic Chemistry
Lauren E LongobardiDouglas W Stephan

Abstract

The stoichiometric reaction of para-methoxyanilines and B(C6F5)3 under H2 results in reduction of the N-bound phenyl ring(s), and subsequent transannular ring closure with elimination of methanol, affording the respective 7-azabicyclo[2.2.1]heptane derivatives.

References

Aug 19, 2007·Angewandte Chemie·Preston A ChaseDouglas W Stephan
Dec 1, 2007·Chemical Communications : Chem Comm·Patrick SpiesDouglas W Stephan
Jul 8, 2008·Angewandte Chemie·Victor SumerinBernhard Rieger
Nov 26, 2009·Angewandte Chemie·Andrew E AshleyDermot O'Hare
Dec 22, 2009·Angewandte Chemie·Douglas W Stephan, Gerhard Erker
Jun 16, 2010·Chemical Communications : Chem Comm·Stephen J GeierDouglas W Stephan
May 4, 2011·Inorganic Chemistry·Douglas W StephanMatthias Ullrich
Feb 18, 2012·Journal of the American Chemical Society·Tayseer MahdiDouglas W Stephan
Mar 1, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Markus LindqvistTimo Repo
Mar 13, 2012·Chemistry, an Asian Journal·Bao-Hua XuGerhard Erker
Apr 17, 2012·Organic & Biomolecular Chemistry·Douglas W Stephan
Nov 7, 2012·Chemical Communications : Chem Comm·Yasutomo Segawa, Douglas W Stephan
Jan 2, 2013·Topics in Current Chemistry·Douglas W Stephan, Gerhard Erker
Apr 24, 2013·Journal of the American Chemical Society·Yongbing Liu, Haifeng Du
Jul 25, 2013·Nature Chemistry·Konstantin ChernichenkoTimo Repo
Aug 16, 2013·Journal of the American Chemical Society·Yongbing Liu, Haifeng Du
Aug 19, 2014·Journal of the American Chemical Society·Simin Wei, Haifeng Du
Sep 25, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Lauren E LongobardiDouglas W Stephan
Oct 22, 2014·Journal of the American Chemical Society·Tayseer Mahdi, Douglas W Stephan
Oct 22, 2014·Journal of the American Chemical Society·Daniel J ScottAndrew E Ashley

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Citations

Jul 28, 2015·Journal of the American Chemical Society·Douglas W Stephan
Jun 10, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Antonio AntiñoloJosé Albaladejo
Mar 26, 2019·Chemistry : a European Journal·Amit K JaiswalRowan D Young
Sep 22, 2017·Acta Crystallographica. Section E, Crystallographic Communications·Sergey N Britvin, Andrey M Rumyantsev
Jan 15, 2019·Chemical Reviews·Marc-André LégaréHolger Braunschweig

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