Bi-stable spin-crossover characteristics of a highly distorted [Fe(1-BPP-COOC2 H5 )2 ](ClO4 )2 ·CH3 CN complex

Dalton Transactions : an International Journal of Inorganic Chemistry
Kuppusamy Senthil KumarMario Ruben

Abstract

A highly distorted high spin Fe(ii)-complex, [Fe(1-BPP-COOC2H5)2](ClO4)2·CH3CN, with a trans-N(pyridine)-Fe-N(pyridine) angle (φ) of 158.83(17)° showed lattice solvent dependent bi-stable spin-state switching characteristics with T1/2 = ca. 233 K and a high thermal hysteresis width (ΔT) of 101 K, for the first cooling and heating cycle, unprecedented for the [Fe(BPP)2]2+ series of complexes; the results presented in this study are fundamentally important and have implications towards the realization of device architectures based on bi-stable SCO complexes.

References

Mar 9, 2006·Chemical Reviews·Michio SoraiYuji Miyazaki
Mar 21, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Chiara CarboneraMalcolm A Halcrow
Nov 21, 2008·Angewandte Chemie·Birgit WeberJaroslava Obel
Jun 28, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Rodrigo González-PrietoMario Ruben
Nov 8, 2014·Physical Chemistry Chemical Physics : PCCP·Sergi VelaJordi Ribas-Arino
Apr 25, 2015·Chemical Society Reviews·Sally Brooker
Mar 9, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Nathalie BridonneauAndrea Cornia
Apr 19, 2017·Chemical Communications : Chem Comm·E TailleurP Guionneau
Jul 20, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Kuppusamy Senthil KumarMario Ruben
Apr 24, 2018·Nanoscale·Enrique BurzuríHerre S J van der Zant
Nov 20, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Víctor García-LópezEugenio Coronado
Dec 7, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Sergi Vela, Hauke Paulsen

❮ Previous
Next ❯

Citations

Dec 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Kuppusamy Senthil KumarMario Ruben
May 19, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yue LiJun Tao
Sep 7, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Kuppusamy Senthil KumarMario Ruben
Jul 16, 2020·Angewandte Chemie·Francisco-Javier Valverde-MuñozJosé Antonio Real
Oct 8, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Kuppusamy Senthil KumarMario Ruben
Dec 8, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Barbora BrachňakováIvan Šalitroš
May 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Izar Capel BerdiellMalcolm A Halcrow
Jun 12, 2021·Chemical Communications : Chem Comm·Izar Capel BerdiellMalcolm A Halcrow
Sep 22, 2021·Inorganic Chemistry·Izar Capel BerdiellMalcolm A Halcrow

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray
differential scanning calorimetry

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.