Biasing Enantiomorph Formation via Geometric Confinement: Nanocorrals for Chiral Induction at the Liquid-Solid Interface

Journal of the American Chemical Society
Johannes SeibelSteven De Feyter

Abstract

Nanocorrals created by scanning probe lithography on covalently modified graphite surfaces are used to induce a chiral bias in the enantiomorphic assembly of a prochiral molecule at the liquid/graphite interface. By controlling the orientation of the nanocorrals with respect to the underlying graphite surface, the nanocorral handedness can be freely chosen and thus a chiral bias in molecular self-assembly is created at an achiral surface solely by the scanning probe lithography process.

References

Mar 7, 2002·Journal of the American Chemical Society·Joshua D Horvath, Andrew J Gellman
Nov 26, 2004·Journal of the American Chemical Society·Manfred ParschauKarl-Heinz Ernst
Jan 26, 2006·Journal of the American Chemical Society·Angelika KühnleFlemming Besenbacher
Oct 12, 2007·Chemical Reviews·T MallatA Baiker
Sep 12, 2009·Angewandte Chemie·Johannes A A W ElemansSteven De Feyter
Jan 15, 2011·Physical Review Letters·Heather L TierneyE Charles H Sykes
Mar 16, 2011·Proceedings of the National Academy of Sciences of the United States of America·Luana Tortora, Oleg D Lavrentovich
Aug 24, 2011·Nature Chemistry·Kazukuni TaharaYoshito Tobe
Nov 22, 2012·Journal of the American Chemical Society·Iris DestoopSteven De Feyter
Jan 21, 2014·Angewandte Chemie·Heike Lorenz, Andreas Seidel-Morgenstern
Jun 13, 2015·Journal of the American Chemical Society·Johannes SeibelKarl-Heinz Ernst
Aug 20, 2015·Nature Communications·Karthik NayaniMohan Srinivasarao
Nov 16, 2016·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Andrew J GellmanJoshua D Horvath
May 17, 2017·Langmuir : the ACS Journal of Surfaces and Colloids·Clarissa F DietrichFrank Giesselmann
Aug 26, 2017·Faraday Discussions·Iris DestoopSteven De Feyter
Oct 19, 2017·Chemical Society Reviews·Francisco Zaera

❮ Previous
Next ❯

Citations

Oct 26, 2018·Physical Chemistry Chemical Physics : PCCP·Lander VerstraeteSteven De Feyter
Feb 2, 2019·Chemical Communications : Chem Comm·Yi HuSteven De Feyter
May 23, 2019·Physical Chemistry Chemical Physics : PCCP·Jinwen HuanQingdao Zeng
Mar 20, 2020·Advanced Materials·Katsuhiko ArigaTakashi Uemura
Dec 9, 2020·Chemical Communications : Chem Comm·Johannes SeibelSteven De Feyter
Aug 14, 2020·Journal of the American Chemical Society·Cheng LuDong Wang
May 25, 2021·Chemical Society Reviews·Lander Verstraete, Steven De Feyter
Jul 21, 2021·Journal of the American Chemical Society·Ana M BragançaSteven De Feyter
Feb 25, 2020·ACS Applied Materials & Interfaces·Sasan ShadpourTorsten Hegmann

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Chemical Communications : Chem Comm
Lander VerstraeteSteven De Feyter
Chemical Society Reviews
Johannes A A W ElemansSteven De Feyter
The Quarterly Journal of Experimental Psychology
A W Heim, K P Watts
© 2022 Meta ULC. All rights reserved