Binary pnictogen azides--an experimental and theoretical study: [As(N3)4]-, [Sb(N3)4]-, and [Bi(N3)5(dmso)]2-

Chemistry : a European Journal
Axel Schulz, Alexander Villinger

Abstract

[PPh(4)][EI(4)] (E=As, Sb, Bi) salts were reacted with four and five equivalents of AgN(3) to form tetraazidopnictates and pentaazidopnictates of the type [PPh(4)][E(N(3))(4)] and [PPh(4)](2)[E(N(3))(5)], respectively. The synthesis of [PPh(4)][P(N(3))(4)] was also attempted from the reaction of P(N(3))(3) with [PPh(4)]N(3), but it yielded only the starting materials. Herein, we report the synthesis and structure elucidation of [PPh(4)][E(N(3))](4) (E=As, Sb) and pentaazidobismuthate, stabilized as the dimethyl sulfoxide (DMSO) anion adduct, [PPh(4)](2)[Bi(N(3))(5)(dmso)]. Successive anion formation along the series E(N(3))(3)+nN(3)(-) (n=1-3) and E(N(3))(5)+N(3)(-) was studied by density functional theory.

References

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Oct 2, 2002·Chemistry : a European Journal·Marcin GonsiorLeo Van Wüllen
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Oct 16, 2007·Angewandte Chemie·Thomas M KlapötkeKarl O Christe
Dec 7, 2007·Angewandte Chemie·Axel Schulz, Alexander Villinger
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Nov 4, 2008·Angewandte Chemie·Wolfgang BaumannAlexander Villinger
Nov 15, 2008·Inorganic Chemistry·P PortiusT Z Todorova
Jul 10, 2009·Inorganic Chemistry·Axel Schulz, Alexander Villinger
Oct 27, 2009·Chemistry : a European Journal·Pekka Pyykkö, Michiko Atsumi
Sep 15, 2010·Angewandte Chemie·Alexander Villinger, Axel Schulz
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Jul 12, 1999·Angewandte Chemie·Karl O ChristeJerry A Boatz

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Citations

Dec 1, 2015·Inorganic Chemistry·William W WilsonKarl O Christe
Dec 1, 2015·Physical Chemistry Chemical Physics : PCCP·Eliano DianaSidney F A Kettle
Jul 16, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Piotr A GuńkaJanusz Zachara
Sep 20, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Rosa Pujales-ParadelaCarlos Platas-Iglesias
May 11, 2013·Inorganic Chemistry·Kati RosenstengelAlexander Villinger
May 28, 2013·Inorganic Chemistry·Benjamin LyhsGeorg Jansen
Mar 29, 2019·Inorganic Chemistry·Sören ArltAlexander Villinger

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