Bis{2-[(2,4-dimethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}bis-(thio-cyanato-κN)cadmium.

Acta Crystallographica. Section E, Structure Reports Online
Mohammad MalekshahianBehrouz Notash

Abstract

The title compound, [Cd(NCS)(2)(C(14)H(14)N(2))(2)], features crystallographic inversion symmetry with the Cd(II) ion located on a centre of inversion. The Cd(II) ion is six-coordinated in a slightly distorted octa-hedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An inter-molecular C-H⋯S hydrogen bond stabilizes the crystal structure.

References

Sep 24, 1999·European Journal of Pharmaceutical Sciences : Official Journal of the European Federation for Pharmaceutical Sciences·S N PandeyaE DeClercq
Oct 16, 2001·European Journal of Medicinal Chemistry·S K SridharA Ramesh
Feb 8, 2005·European Journal of Medicinal Chemistry·Perumal PanneerselvamSeshaiah Krishnan Sridhar
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Jan 1, 2008·Acta Crystallographica. Section E, Structure Reports Online·Mohamad Reza Talei Bavil OlyaiHamid Reza Khavasi
Jul 15, 2011·Acta Crystallographica. Section E, Structure Reports Online·Sedigheh LoniBehrouz Notash

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