Bismuth as a versatile cation for luminescence in coordination polymers from BiX3 /4,4'-bipy: understanding of photophysics by quantum chemical calculations and structural parallels to lanthanides

Dalton Transactions : an International Journal of Inorganic Chemistry
Jens R SorgKlaus Müller-Buschbaum

Abstract

Coordination polymers (CPs) with bismuth(iii) as a connectivity centre have been prepared from BiX3 (X = Cl-I) and 4,4'-bipyridine (bipy) in order to implement Bi-based luminescence. The products were obtained via different synthetic routes such as solution chemistry, melt syntheses or mechanochemical reactions. Five neutral and anionic 1D-CPs are presented that show a chemical parallel to trivalent lanthanides forming isostructural or closely related 1D-CPs, of which five additional compounds are described. Bi3+ proves to be a versatile cation for luminescence resulting from energy transfer processes between a metal and a ligand in the presented CPs. Quantum chemical calculations were carried out to investigate Bi3+-participation in the luminescence processes. The calculated results allow an assignment of the bright transitions composed of mainly metal-to-ligand-charge transfer (MLCT) character. These results show that Bi3+ can form strongly luminescent coordination compounds with N-donor ligands.

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Citations

Sep 6, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Alyssa K AdcockKarah E Knope
Aug 18, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Alyssa K AdcockKarah E Knope
Apr 2, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jens R SorgKlaus Müller-Buschbaum
Oct 8, 2020·Angewandte Chemie·Matthias HämmerHenning A Höppe
Jun 29, 2021·Inorganic Chemistry·Laura A MaurerMichael P Marshak
Sep 9, 2020·Inorganic Chemistry·Csilla FeketeDominikus Heift
Oct 12, 2021·Inorganic Chemistry·Alexander C MarwitzKarah E Knope

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