Bismuth(III) Complex of the [S4]•- Radical Anion: Dimer Formation via Pancake Bonds

Journal of the American Chemical Society
Ryan J SchwammChristopher M Fitchett

Abstract

Reaction of bismuth(II) compounds with sulfur gives mixtures of [Bi(NONR)]2(μ2-Sn) (NONR = [O(SiMe2NR)2]2-). Examples for n = 1 and 3 have been crystallographically verified for R = 2,6-iPr2C6H3 (Dipp) and R = tBu, and the pentasulfide (n = 5) for R = Dipp. The corresponding product from reaction with the new Bi(II) radical Bi(NONAr‡)• (Ar‡ = C6H2(CHPh2)2-tBu-2,6,4) exists as the dimer [Bi(NONAr‡)(S4)]2, with π*(SOMO)-π*(SOMO) interactions linking the sulfur chains through trans-antarafacial pancake bonds.

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Citations

Mar 27, 2018·Angewandte Chemie·Ryan J SchwammChristopher M Fitchett
Dec 15, 2018·Angewandte Chemie·Ryan J SchwammMartyn P Coles
Jan 3, 2019·Chemistry, an Asian Journal·Ryan J SchwammMartyn P Coles
Feb 12, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Ryan J SchwammMartyn P Coles
Aug 28, 2019·Chemistry : a European Journal·Ryan J Schwamm, Martyn P Coles
Jul 30, 2019·Chemistry : a European Journal·Monika KořenkováLibor Dostál
Feb 13, 2020·Chemistry : a European Journal·Crispin Lichtenberg
Dec 22, 2019·Chemistry : a European Journal·Matthew J EvansJ Robin Fulton
Jan 11, 2018·Chemical Communications : Chem Comm·R J SchwammC M Fitchett
Oct 8, 2020·Physical Chemistry Chemical Physics : PCCP·Paweł Rejmak
Dec 17, 2020·Chemistry : a European Journal·Anna HanftCrispin Lichtenberg
Apr 17, 2021·Chemical Communications : Chem Comm·Crispin Lichtenberg
Nov 16, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Santiago Alvarez

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