Blue-shifted aggregation-induced enhancement of a Sn(iv) fluoride complex: the role of fluorine in luminescence enhancement

Chemical Communications : Chem Comm
Wooseok KiJing Li

Abstract

A new type of blue-shifted aggregation-induced emission enhancement was observed for a Sn(iv) fluoride complex, resulting in strong emission in the solid state as compared with that in solutions. The fluorinated Sn(iv) complex has a significantly more intense emission efficiency compared to the chlorinated Sn(iv) complex, which is attributed to stronger σ bonding.

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