Borylene Insertion into Cage B-H Bond: A Route to Electron-Precise B-B Single Bond

Journal of the American Chemical Society
Hao WangZuowei Xie

Abstract

A new strategy to construct electron-precise B-B single bond via direct borylene insertion into B-H bond is described. Reduction of bromoborylene stabilized by carborane-fused silylenes with 2 equiv of sodium gives a new compound with a B-B single bond. Both experimental and density functional theory results suggest that such an electron-precise B-B single bond is formed via in situ generated borylene insertion into B-H bond.

References

Jul 3, 2007·Journal of the American Chemical Society·Xiaodu FuZuowei Xie
Oct 27, 2007·Angewandte Chemie·Rupam DindaHans-Jörg Himmel
Jun 18, 2009·Angewandte Chemie·Oxana CiobanuHans-Jörg Himmel
Apr 15, 2002·Angewandte Chemie·Holger BraunschweigKrzysztof Radacki
Dec 2, 2009·Chemistry : a European Journal·Rajendra S GhadwalDietmar Stalke
Aug 4, 2010·Journal of the American Chemical Society·Kyoko NozakiDennis P Curran
Oct 30, 2010·Angewandte Chemie·Guido D FreyGuy Bertrand
Apr 12, 2011·Chemical Communications : Chem Comm·Yumi HayashiKyoko Nozaki
May 21, 2011·Journal of the American Chemical Society·Mariham Y AbrahamGregory H Robinson
Jun 4, 2011·Inorganic Chemistry·Yuzhong Wang, Gregory H Robinson
Jun 30, 2011·Journal of the American Chemical Society·Yoshiaki ShojiKohei Tamao
Sep 17, 2011·Angewandte Chemie·Nikola SchulenbergHans-Jörg Himmel
Oct 29, 2011·Journal of the American Chemical Society·Philipp BissingerKatharina Wagner
Nov 8, 2011·Angewandte Chemie·Holger Braunschweig, Frank Guethlein
Jun 19, 2012·Chemistry : a European Journal·Holger BraunschweigLisa Zöllner
Jun 22, 2012·Nature Chemistry·Holger BraunschweigAlexander Damme
Jul 20, 2013·Journal of the American Chemical Society·Xiben Li, Dennis P Curran
Jul 23, 2013·Angewandte Chemie·Heather C JohnsonAndrew S Weller
Feb 21, 2014·Angewandte Chemie·Holger BraunschweigStefan Ullrich
Mar 29, 2014·Angewandte Chemie·Alexander HübnerMatthias Wagner
Aug 7, 2014·Chemical Communications : Chem Comm·Holger Braunschweig, Christian Hörl
Feb 28, 2015·Journal of the American Chemical Society·Alexander HübnerMatthias Wagner
Jun 19, 2015·Nature·Holger BraunschweigQing Ye
Jul 30, 2015·Angewandte Chemie·Johannes LandmannMaik Finze
Dec 17, 2015·Journal of the American Chemical Society·Nicole ArnoldWilliam C Ewing
Apr 26, 2016·Journal of the American Chemical Society·Thomas KaeseMatthias Wagner
Jun 17, 2016·Journal of the American Chemical Society·Lingbing KongRei Kinjo
Jul 19, 2016·Chemistry : a European Journal·Sabrina Würtemberger-PietschUdo Radius
Jul 20, 2016·Chemical Reviews·Emily C NeeveTodd B Marder
Sep 15, 2016·Angewandte Chemie·Étienne RochetteFrédéric-Georges Fontaine
Nov 20, 2016·Angewandte Chemie·Merle ArrowsmithTom E Stennett
Dec 13, 2016·Chemical Society Reviews·Ana B CuencaElena Fernández
Jan 20, 2017·Journal of the American Chemical Society·Holger BraunschweigQing Ye
Mar 17, 2017·Nature Communications·Ruofei ChengZuowei Xie
May 26, 2017·Angewandte Chemie·Thomas KaeseMatthias Wagner
Jun 4, 2017·Angewandte Chemie·Michele Soleilhavoup, Guy Bertrand
Sep 9, 2017·Journal of the American Chemical Society·Hao WangZuowei Xie
Nov 9, 2017·Angewandte Chemie·Anne-Frédérique PécharmanMary F Mahon

❮ Previous
Next ❯

Citations

Apr 16, 2019·Angewandte Chemie·Peng-Fei CuiGuo-Xin Jin
May 30, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Samir Kumar SarkarHerbert W Roesky
Aug 26, 2020·Angewandte Chemie·Matthias DriessAles Ruzicka
Jun 12, 2019·Chemical Science·Merle ArrowsmithHolger Braunschweig
Jul 14, 2021·Journal of the American Chemical Society·Gayathri B GangeDmitry V Peryshkov
Dec 1, 2020·Journal of the American Chemical Society·Anna Kataki-AnastasakouEllen M Sletten
Sep 18, 2020·Journal of the American Chemical Society·Hui ZhangQing Ye
Oct 16, 2021·Inorganic Chemistry·Jun FanCheuk-Wai So

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

© 2022 Meta ULC. All rights reserved