Buchwald-Hartwig amination using Pd(i) dimer precatalysts supported by biaryl phosphine ligands

Dalton Transactions : an International Journal of Inorganic Chemistry
Kent O KirlikovaliAlexander M Spokoyny

Abstract

We report the synthesis of air-stable Pd(i) dimer complexes featuring biaryl phosphine ligands. Catalytic experiments suggest that these complexes are competent precatalysts that can mediate cross-coupling amination reactions between aryl halides with both aliphatic and aromatic amine nucleophiles. This work represents an expansion of the air-stable precatalyst toolbox for Pd-catalyzed cross-coupling transformations.

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Citations

Feb 6, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Michelle MontgomeryRobin B Bedford
Mar 29, 2019·Chemistry : a European Journal·Simon WagschalLaurence Grimaud
Oct 16, 2020·Angewandte Chemie·Christoph FrickeFranziska Schoenebeck
Jan 7, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Daniel Y ZhouMatthew F Cain

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Methods Mentioned

BETA
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