C-Glycosides of 2-amino-2-deoxy sugars. beta-C-Glycosides and 1,1-disubstituted variants

Organic Letters
Yan Liu, Timothy Gallagher

Abstract

[reaction: see text] C(1)-Substituted anomeric selenides, derived from azidoselenation of C(1)-methylated glycals, provide access to anomeric radical reactivity that has been used to generate beta-C-glycosides and 1,1-disubstituted C-glycosides based on galacto, gluco, and manno variants of N-acetyl-2-amino sugars.

Citations

Jan 28, 2009·Organic Letters·Hegui GongMichel R Gagné
Jul 5, 2008·Accounts of Chemical Research·Richard R Schmidt, Yashwant D Vankar
Sep 16, 2017·Chemical Reviews·You Yang, Biao Yu
Aug 16, 2011·Organic Letters·Daisuke UrabeMasayuki Inoue

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