C(5)N(-) anion and new carbenic isomers of cyanodiacetylene: a matrix isolation IR study

The Journal of Chemical Physics
Anne CoupeaudJean-Pierre Aycard

Abstract

Products of the vacuum-UV photolysis of cyanodiacetylene (HC(5)N) in solid argon -- the anion C(5)N(-), imine HNC(5), and the branched carbene C(4)(H)CN -- have been identified by IR absorption spectroscopy, in addition to the already discovered isonitrile HC(4)NC. Spectral assignments were assisted by deuterium substitution experiments, by BD(T) calculations, and by the results of a recent density functional theory study.

References

Oct 15, 2005·Angewandte Chemie·Yann Trolez, Jean-Claude Guillemin
Oct 20, 2006·The Journal of Physical Chemistry. a·Leonid KhriachtchevMarkku Räsänen
May 5, 2007·The Journal of Chemical Physics·Anne CoupeaudJean-Pierre Aycard
Apr 25, 2008·The Journal of Chemical Physics·Robert KołosPeter Botschwina
May 2, 2008·The Journal of Chemical Physics·Michał TurowskiRobert Kołos
Oct 1, 1968·Applied Optics·D Davis, W Braun

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Citations

May 23, 2012·The Journal of Physical Chemistry. a·Marcin GronowskiJoanna Sadlej
May 4, 2013·The Journal of Physical Chemistry. a·Marcin Gronowski, Robert Kołos
Mar 14, 2014·The Journal of Physical Chemistry. a·A ToumiN Piétri
Aug 7, 2008·The Journal of Chemical Physics·Peter Botschwina, Rainer Oswald
Feb 12, 2015·The Journal of Chemical Physics·I Couturier-TamburelliR Kołos
Dec 6, 2016·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Michał TurowskiRobert Kołos
Jul 6, 2016·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·E Cristina Stanca-KapostaKnut R Asmis
Feb 1, 2018·Physical Chemistry Chemical Physics : PCCP·Wojciech SkomorowskiAnna I Krylov
Apr 13, 2019·The Journal of Physical Chemistry. a·Joanna ZapałaMarcin Gronowski

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Methods Mentioned

BETA
NMR

Software Mentioned

GAUSSIAN

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