Calix[4]arene-supported mononuclear lanthanide single-molecule magnet

Inorganic Chemistry
Feng GaoJing-Lin Zuo

Abstract

Three new single paramagnetic lanthanide-based complexes, [Ln(L)(LOEt)] (Ln(3+) = Dy(3+), Tb(3+), and Ho(3+)), are synthesized with the multidentate calix[4]arene ligand H2L (H2L = 5,11,17,23-tetrakis(1,1-dimethylethyl)-25,27-dihydroxy-26,28-dimethoxycalix[4]arene) and Kläui's tripodal ligand LOEt(-) (LOEt(-) = (η(5)-cyclopentadienyl)tris(diethylphosphito-p)cobaltate(III)). All of the complexes have been characterized by single crystal X-ray diffraction analysis, thermal stability, absorption spectra, and magnetization measurements. The magnetic properties and magnetostructural correlation in this seven-coordinated system are investigated. The dysprosium complex 1 shows typical single-molecule magnetic behavior with characteristic magnetic hysteresis loops and the slow relaxation of magnetization.

References

Apr 12, 2001·Nature·M N Leuenberger, D Loss
Jan 28, 2003·Angewandte Chemie·Dante Gatteschi, Roberta Sessoli
Jan 15, 2004·Journal of the American Chemical Society·Shutaro OsaJerzy Mrozinski
Feb 26, 2008·Nature Materials·Lapo Bogani, Wolfgang Wernsdorfer
Jun 19, 2008·Journal of the American Chemical Society·Murad A AldamenAlejandro Gaita-Ariño
Nov 26, 2009·Angewandte Chemie·Georgios KarotsisEuan K Brechin
Jun 10, 2010·Journal of the American Chemical Society·Yun-Nan GuoHong-Jie Zhang
Jul 27, 2010·Chemical Communications : Chem Comm·Hongshan KeJinkui Tang
Aug 4, 2010·Journal of the American Chemical Society·Georgios KarotsisEuan K Brechin
Feb 22, 2011·Chemical Society Reviews·Filippo Troiani, Marco Affronte
Mar 16, 2011·Journal of the American Chemical Society·Shang-Da JiangSong Gao
May 20, 2011·Chemistry : a European Journal·Stephanie M TaylorEuan K Brechin
Sep 10, 2011·Chemical Communications : Chem Comm·Sergio SanzScott J Dalgarno
Sep 22, 2011·Chemistry : a European Journal·Ye BiSong Gao
Oct 29, 2011·Journal of the American Chemical Society·Matthew JeleticMuralee Murugesu
Jan 4, 2012·Angewandte Chemie·Mei LiuHongjie Zhang
Feb 7, 2012·Chemistry : a European Journal·Gong-Jun ChenDai-Zheng Liao
Feb 9, 2012·Chemical Communications : Chem Comm·Hailong WangJianzhuang Jiang
Feb 24, 2012·Inorganic Chemistry·Shang-Da JiangSong Gao
Aug 22, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Keiichi KatohMasahiro Yamashita
Aug 30, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Min-Xia YaoJing-Lin Zuo
Nov 13, 2012·Angewandte Chemie·Shuang-Yan LinHong-Jie Zhang
Dec 5, 2012·Angewandte Chemie·Marie-Emmanuelle BoulonRoberta Sessoli
Jan 22, 2013·Chemical Society Reviews·Fatemah Habib, Muralee Murugesu
Apr 5, 2013·Chemical Reviews·Daniel N WoodruffRichard A Layfield
Jun 12, 2013·Chemistry : a European Journal·Min RenLi-Min Zheng
Jul 25, 2013·Inorganic Chemistry·Min RenMasahiro Yamashita
Aug 9, 2013·Chemical Communications : Chem Comm·Huaqiao TanWuping Liao

❮ Previous
Next ❯

Citations

Nov 26, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Jian ZhouQiuling Tang
Jan 11, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Feng GaoXiu-Ling Li
Apr 8, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Lidia Rosado Piquer, E Carolina Sañudo
Aug 4, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jing-Yuan GeJing-Lin Zuo
Oct 23, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Sourav BiswasVadapalli Chandrasekhar
Feb 20, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Feng TanQiuling Tang
Apr 6, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Feng GaoXiaoyu Chen
Nov 6, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Shuang-Yan LinJinkui Tang
Nov 6, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Feng GaoYue Zhao
Mar 20, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jian ZhouXiao-Feng Tan
Aug 1, 2015·Chemistry : a European Journal·Małgorzata HołyńskaMathieu Rouzières
Oct 12, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Chao BaiGanglin Xue
Jul 29, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Peter HahnBerthold Kersting
Jan 23, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Ehsan Bahojb NoruziHossein Samadi Kafil
Jun 24, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Yushu JiaoPaul Kögerler
Jul 26, 2021·Chemical Communications : Chem Comm·Marjan HosseinzadehPaul Kögerler

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.