Capture of toxic gases in MOFs: SO2, H2S, NH3 and NO x .

Chemical Science
Eva Martínez-AhumadaIlich A Ibarra

Abstract

MOFs are promising candidates for the capture of toxic gases since their adsorption properties can be tuned as a function of the topology and chemical composition of the pores. Although the main drawback of MOFs is their vulnerability to these highly corrosive gases which can compromise their chemical stability, remarkable examples have demonstrated high chemical stability to SO2, H2S, NH3 and NO x . Understanding the role of different chemical functionalities, within the pores of MOFs, is the key for accomplishing superior captures of these toxic gases. Thus, the interactions of such functional groups (coordinatively unsaturated metal sites, μ-OH groups, defective sites and halogen groups) with these toxic molecules, not only determines the capture properties of MOFs, but also can provide a guideline for the desigh of new multi-functionalised MOF materials. Thus, this perspective aims to provide valuable information on the significant progress on this environmental-remediation field, which could inspire more investigators to provide more and novel research on such challenging task.

References

Jan 1, 1984·Critical Reviews in Toxicology·R O BeauchampD A Andjelkovich
Jan 1, 1994·Environmental Pollution·A FangmeierH J Jäger
Feb 1, 2007·Journal of the American Chemical Society·Bo XiaoRussell E Morris
Jul 17, 2008·Journal of the American Chemical Society·Alistair C McKinlayRussell E Morris
Aug 20, 2008·Proceedings of the National Academy of Sciences of the United States of America·David BrittOmar M Yaghi
Apr 8, 2009·Journal of the American Chemical Society·Xiaoliang MaChunshan Song
Apr 23, 2009·Chemical Society Reviews·Jian-Rong LiHong-Cai Zhou
Jul 17, 2009·Journal of the Air & Waste Management Association·Joo-Youp LeeY Jeffery Yang
Sep 3, 2010·Nature Reviews. Drug Discovery·Roberto Motterlini, Leo E Otterbein
Sep 10, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Camille PetitTeresa J Bandosz
Oct 15, 2010·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Camille PetitTeresa J Bandosz
Jun 22, 2011·Chemical Communications : Chem Comm·Ilich A IbarraMartin Schröder
Mar 2, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Phoebe K AllanRussell E Morris
Dec 1, 2012·Science·S ReisM Williams
Aug 29, 2013·Environmental Science and Pollution Research International·Sailesh N BeheraRajasekhar Balasubramanian
Sep 21, 2013·Chemical Communications : Chem Comm·Sébastien VaesenGuy De Weireld
Feb 15, 2014·Circulation Research·David J Polhemus, David J Lefer
May 8, 2015·Angewandte Chemie·Elena López-MayaJorge A R Navarro
Aug 13, 2015·Angewandte Chemie·Maarten G GoestenF Matthias Bickelhaupt
Oct 1, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael J KatzOmar K Farha
Nov 6, 2015·Journal of the American Chemical Society·Hillary A Henthorn, Michael D Pluth
Apr 14, 2016·Angewandte Chemie·Gregory W PetersonJoseph A Rossin
Jul 16, 2016·Journal of the American Chemical Society·Adam J RiethMircea Dincă
Aug 17, 2016·Advanced Materials·Mathew SavageMartin Schröder
Dec 26, 2016·Journal of Hazardous Materials·Xinpeng Liu, Rui Wang
Feb 16, 2017·Nature Communications·L Marleny Rodríguez-AlbeloJorge A R Navarro
Oct 5, 2017·ACS Applied Materials & Interfaces·Sebastian GlombChristoph Janiak
Jan 25, 2018·Advanced Materials·Stefano DissegnaRoland A Fischer
Feb 8, 2018·Analytical Chemistry·Chan YangXiao-Bing Zhang
Feb 10, 2018·Journal of the American Chemical Society·Adam J Rieth, Mircea Dincă
Aug 12, 2018·Angewandte Chemie·Harry G W GodfreyMartin Schröder
Sep 25, 2018·Nature Climate Change·Raquel A SilvaGuang Zeng
Nov 13, 2018·Journal of the American Chemical Society·Joseph H CarterMartin Schröder

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Citations

Aug 12, 2021·ACS Applied Materials & Interfaces·Alfredo López-OlveraIlich A Ibarra

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