Carbeniophosphines versus Phosphoniocarbenes: The Role of the Positive Charge

Chemistry, an Asian Journal
Yves Canac

Abstract

The chemistry of carbeniophosphines and phosphoniocarbenes, which have general structures derived formally from the three-component "carbene/phosphine/positive charge" association, is presented. These two complementary classes of carbon-phosphorus-based ligands, defined by the presence of an inverted cationic coordinating structure (C+ ∼P: vs. P+ ∼C:) have the common purpose of positioning a positive charge in the vicinity of the metal center. Through selected examples, the synthetic methods, coordination properties, and general reactivity of both cationic species is described. Particular emphasis is placed on the influence of the positive charge on the respective chemical behavior of the two classes of compound.

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Citations

Jan 12, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Rachid TaakiliYves Canac
Feb 20, 2020·Chemical Communications : Chem Comm·Cécile BarthesVincent César
May 7, 2020·Chemical Communications : Chem Comm·Pablo RíosSalvador Conejero
May 14, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Rachid Taakili, Yves Canac
Nov 21, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Mario Cicač-HudiDietrich Gudat
Dec 22, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Mario Cicač-HudiDietrich Gudat
Dec 11, 2021·Chemistry : a European Journal·Tobias StalderViktoria H Gessner

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