Carbonates, thiocarbonates, and the corresponding monoalkyl derivatives. 1. Their preparation and isotropic (13)C NMR chemical shifts

Inorganic Chemistry
D StueberRobert W Parry

Abstract

Three series of potassium carbonate and thiocarbonate salts were synthesized, and the corresponding (13)C isotropic solid-state NMR and the aqueous solution (13)C and (1)H NMR data were collected. The series of compounds that were studied consists of (1) the parent compounds, i.e., potassium carbonate, K(2)CO(3), potassium hydrogen carbonate, KHCO(3), potassium monothiocarbonate, K(2)CO(2)S, potassium dithiocarbonate, K(2)COS(2), and potassium trithiocarbonate, K(2)CS(3), (2) the oxygen monoalkyl substituted derivatives of the parent compounds (OR series), i.e., three potassium O-alkylcarbonates, KO(2)COR, three potassium O-alkylmonothiocarbonates, KOSCOR, and three potassium O-alkyldithiocarbonates, KS(2)COR, all with R = CH(3), CH(2)CH(3), CH(CH(3))(2), and (3) the sulfur monoalkyl substituted derivatives of the parent compounds (SR series), i.e., two potassium S-alkylmonothiocarbonates, KO(2)CSR; two potassium S-alkyldithiocarbonates, KOSCSR, and two potassium S-alkyltrithiocarbonates, KS(2)CSR, all with R = CH(3) or CH(2)CH(3). The preparation and proper characterization of KO(2)CSR and KOSCSR with R = CH(3) and CH(2)CH(3) along with new IR and X-ray powder diffraction data for several other compounds in the series are repo...Continue Reading

References

Sep 15, 1988·Physical Review A: General Physics·A D Becke
Jun 1, 1983·Proceedings of the National Academy of Sciences of the United States of America·L Pauling

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Citations

Mar 15, 2011·Progress in Nuclear Magnetic Resonance Spectroscopy·Julio C Facelli
Sep 1, 2016·Inorganic Chemistry·Skylar J FerraraJames P Donahue
Jan 5, 2017·Journal of the American Chemical Society·Poonam SinghDaniel A Buttry
Jun 15, 2017·Journal of the American Chemical Society·Julie AndrezMarinella Mazzanti
Dec 2, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Clément CampMarinella Mazzanti
Aug 1, 2014·Angewandte Chemie·Julie AndrezMarinella Mazzanti
Jul 3, 2013·Chemical Communications : Chem Comm·Masatoshi IshidaJonathan L Sessler
Sep 1, 2016·Chemical Science·Julie AndrezMarinella Mazzanti
Oct 9, 2003·Chemical Reviews·Daniela Belli Dell'AmicoGuido Pampaloni

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