Catalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysis.

Organic Letters
M Kevin Brown, E J Corey

Abstract

This paper reports a method for highly enantioselective Diels-Alder reaction with an acetylene equivalent to produce chiral-bridged dienes. These dienes, by coordination to Rh(I), can serve as catalysts for the enantioselective addition of vinyl or aryl groups to alpha,beta-unsaturated ketones.

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Citations

Nov 3, 2010·Journal of the American Chemical Society·W Christopher BoydF Dean Toste
Aug 19, 2011·Chemical Communications : Chem Comm·Takahiro NishimuraTamio Hayashi
Dec 17, 2014·Natural Product Reports·Martin J Schnermann, Ryan A Shenvi
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Mar 8, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Duncan CarmichaelMarek Stankevič
Jan 22, 2013·European Journal of Organic Chemistry·Yuan-Xi Liao, Qiao-Sheng Hu
Dec 14, 2011·Chemistry : a European Journal·Silvia GosiewskaJohn M Brown
Jan 15, 2013·Angewandte Chemie·Michael E JungQuentin Perron
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Oct 26, 2012·Chemical Communications : Chem Comm·Daniel Müller, Alexandre Alexakis
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Aug 19, 2010·Organic Letters·Ryo ShintaniTamio Hayashi
Apr 24, 2013·Journal of the American Chemical Society·Yongbing Liu, Haifeng Du
Jun 26, 2013·The Journal of Organic Chemistry·Noureddine KhiarInmaculada Fernández
Dec 2, 2020·Accounts of Chemical Research·Tomohiro YasukawaShu Kobayashi
Nov 9, 2018·Journal of the American Chemical Society·Manabu HatanoKazuaki Ishihara

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