Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes

Angewandte Chemie
John R Coombs, James P Morken

Abstract

Terminal alkenes are readily available functional groups which appear in α-olefins produced by the chemical industry, and they appear in the products of many contemporary synthetic reactions. While the organic transformations that apply to alkenes are amongst the most studied reactions in all of chemical synthesis, the number of reactions that apply to nonactivated terminal alkenes in a catalytic enantioselective fashion is small in number. This Minireview highlights the cases where stereocontrol in catalytic reactions of 1-alkenes is high enough to be useful for asymmetric synthesis.

References

Feb 14, 2003·Organic Letters·Arab K El-QisairiPatrick M Henry
Apr 10, 2003·Chemical Reviews·Hans-Ulrich Reissig, Reinhold Zimmer
Apr 10, 2004·Proceedings of the National Academy of Sciences of the United States of America·Ei-Ichi NegishiTibor Novak
Jun 10, 2004·Journal of the American Chemical Society·Reema K ThaljiRobert G Bergman
Feb 24, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Ei-ichi Negishi
Sep 8, 2005·Journal of the American Chemical Society·Dmitry KarshtedtT Don Tilley
Sep 30, 2005·Natural Product Reports·Joseph P Michael
Feb 9, 2006·Journal of the American Chemical Society·Junliang ZhangChuan He
Apr 7, 2006·Organic Letters·Rebecca M WilsonJonathan A Ellman
Oct 26, 2006·Journal of the American Chemical Society·Marco ColladonGiorgio Strukul
Jun 7, 2007·Annual Review of Psychology·Donald D PriceFabrizio Benedetti
Nov 14, 2007·Accounts of Chemical Research·Jerzy Klosin, Clark R Landis
Feb 14, 2008·Angewandte Chemie·Nadine Bongers, Norbert Krause
Apr 30, 2008·Chemistry : a European Journal·Ross A Widenhoefer
Jul 11, 2008·Journal of the American Chemical Society·Hidehiro SuematsuTsutomu Katsuki
Aug 30, 2008·Chemical Reviews·Thomas E MüllerMizuki Tada
Mar 31, 2009·Journal of the American Chemical Society·Zhibin ZhangRoss A Widenhoefer
Jul 9, 2009·Chemical Communications : Chem Comm·Velusamy SubbarayanX Peter Zhang
Aug 26, 2009·Journal of the American Chemical Society·Laura T KlimanJames P Morken
Oct 23, 2009·Chemical Society Reviews·Cheryl A Carson, Michael A Kerr
Nov 26, 2009·Journal of the American Chemical Society·Stepan ChuprakovValery V Fokin
Feb 6, 2010·Journal of the American Chemical Society·Neil GrimsterValery V Fokin
Jul 10, 2010·Organic & Biomolecular Chemistry·Tom G Driver
Aug 5, 2010·Journal of the American Chemical Society·Wojciech I DzikBas de Bruin
Sep 18, 2010·Journal of the American Chemical Society·Richard I McDonaldClark R Landis
Oct 5, 2010·Journal of the American Chemical Society·Amanda D WorthyKian L Tan
Oct 13, 2010·Angewandte Chemie·Alexander L ReznichenkoKai C Hultzsch
Nov 23, 2010·Chemical Reviews·Piet W N M van LeeuwenMontserrat Diéguez

❮ Previous
Next ❯

Citations

Mar 16, 2016·Journal of the American Chemical Society·István Gábor Molnár, Ryan Gilmour
May 12, 2016·Journal of the American Chemical Society·Yumeng Xi, John F Hartwig
Jul 20, 2016·Chemical Reviews·Emily C NeeveTodd B Marder
Apr 12, 2017·Chemical Communications : Chem Comm·Christopher Sandford, Varinder K Aggarwal
Apr 30, 2017·Chemical Science·Daniel J BlairVarinder K Aggarwal
Dec 17, 2016·Angewandte Chemie·James W B FyfeAllan J B Watson
Jun 20, 2017·The Journal of Organic Chemistry·Changduo PanJin-Tao Yu
Jul 1, 2017·Journal of the American Chemical Society·James R SmithVarinder K Aggarwal
Jul 13, 2017·Journal of the American Chemical Society·Stephen R Sardini, M Kevin Brown
Mar 8, 2018·Chemistry : a European Journal·Kodai KatoMasahiro Miura
Jun 19, 2018·Chemical Society Reviews·Markus D Kärkäs
Sep 27, 2018·Angewandte Chemie·Felix ScheidtRyan Gilmour
Sep 27, 2018·Angewandte Chemie·Rebecca M DemmingBernhard Hauer
Jan 25, 2019·Angewandte Chemie·Marc Montesinos-MagranerAbraham Mendoza
Feb 12, 2019·Angewandte Chemie·Wang WangGuoyin Yin
Apr 17, 2019·Angewandte Chemie·Guangzhu WangSenmiao Xu
May 6, 2019·Angewandte Chemie·Yangyang LiGuoyin Yin
Sep 5, 2019·Angewandte Chemie·Conghui TangDavid Sarlah
Dec 5, 2019·Angewandte Chemie·Yuqiang LiGuoyin Yin
May 22, 2020·Angewandte Chemie·Ting LiuCongyang Wang
Sep 24, 2020·Organic & Biomolecular Chemistry·Shuang YangZhenhua Ding
Feb 9, 2020·Nature Communications·Xuzhong ShenZhan Lu
Jan 23, 2021·Journal of the American Chemical Society·Chisato Wata, Takuya Hashimoto
Jan 16, 2021·Angewandte Chemie·Bart HerléAlois Fürstner
Apr 6, 2021·Organic Letters·Xin LiQiuling Song
Jan 28, 2021·Annual Review of Physical Chemistry·Yoo Seok LeeShelley D Minteer
May 21, 2021·Accounts of Chemical Research·Jun GuoZhan Lu

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.