PMID: 9438841Feb 7, 1998Paper

Catalytic galactose oxidase models: biomimetic Cu(II)-phenoxyl-radical reactivity

Science
Y WangT D Stack

Abstract

Biomimetic functional models of the mononuclear copper enzyme galactose oxidase are presented that catalytically oxidize benzylic and allylic alcohols to aldehydes with O2 under mild conditions. The mechanistic fidelity between the models and the natural system is pronounced. Modest structural mimicry proves sufficient to transfer an unusual ligand-based radical mechanism, previously unprecedented outside the protein matrix, to a simple chemical system.

References

May 20, 1994·Journal of Molecular Biology·N ItoP F Knowles
Mar 1, 1993·Biophysical Journal·M M Whittaker, J W Whittaker

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Citations

Apr 1, 2000·Current Opinion in Chemical Biology·V MahadevanT D Stack
Jun 22, 2013·Chemical Reviews·Scott E AllenMarisa C Kozlowski
Apr 28, 2011·Inorganic Chemistry·Wojciech I DzikBas de Bruin
Mar 1, 2012·Inorganic Chemistry·Dalia RokhsanaRobert K Szilagyi
Jun 6, 2012·Inorganic Chemistry·Manas Kumar BiswasPrasanta Ghosh
Aug 25, 2011·Journal of the American Chemical Society·Jessica M Hoover, Shannon S Stahl
Jan 16, 2013·Journal of the American Chemical Society·Jessica M HooverShannon S Stahl
Oct 23, 2008·Journal of the American Chemical Society·Tim StorrT Daniel P Stack
Mar 4, 2009·Journal of the American Chemical Society·Neal P MankadJonas C Peters
Aug 27, 2009·Journal of the American Chemical Society·Takuya KurahashiHiroshi Fujii
Mar 3, 2010·Journal of the American Chemical Society·Cameron A LippertJake D Soper
Sep 16, 2009·Chemical Communications : Chem Comm·Shahulhameed SabiahNarasimha N Murthy
Nov 9, 2011·Proceedings of the National Academy of Sciences of the United States of America·Pratik VermaT Daniel P Stack
Oct 13, 2005·Biological Chemistry·Albrecht BerkesselKatja Glaubitz
Mar 5, 2014·Chemical Reviews·Edward I SolomonLi Tian
Nov 8, 2001·Proceedings of the National Academy of Sciences of the United States of America·L Xie, W A van der Donk
Sep 21, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Isabelle SylvestreMalcolm A Halcrow
May 15, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Alex JohnPrasenjit Ghosh
Jun 27, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Amit Saha RoyPrasanta Ghosh
May 8, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Lin ChengZhijian Wu
Jul 10, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Ritu MishraRupendranath Banerjee
May 11, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Lin ChengZhijian Wu
May 5, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Sudipta ChatterjeeSreebrata Goswami
May 12, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Tim J DunnTim Storr
Aug 16, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Oindrila Das, Tapan Kanti Paine
Mar 12, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Manas Kumar BiswasPrasanta Ghosh
May 16, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Ravinder KumarPavan Mathur
Dec 24, 2015·Journal of the American Chemical Society·Scott D McCann, Shannon S Stahl

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