Catalytic one-electron reduction of uranyl(VI) to Group 1 uranyl(V) complexes via Al(III) coordination

Chemical Communications : Chem Comm
Markus ZegkeJason B Love

Abstract

Reactions between the uranyl(VI) Pacman complex [(UO2)(py)(H2L)] of the Schiff-base polypyrrolic macrocycle L and Tebbe's reagent or DIBAL result in the first selective reductive functionalisation of the uranyl oxo by Al to form [(py)(R2AlOUO)(py)(H2L)] (R = Me or (i)Bu). The clean displacement of the oxo-coordinated Al(III) by Group 1 cations has enabled the development of a one-pot, DIBAL-catalysed reduction of the U(VI) uranyl complexes to a series of new, mono-oxo alkali-metal-functionalised uranyl(V) complexes [(py)3(MOUO)(py)(H2L)] (M = Li, Na, K).

References

Dec 21, 2004·Inorganic Chemistry·Polly L ArnoldJason B Love
Oct 10, 2006·Chemical Communications : Chem Comm·Jean-Claude BerthetMichel Ephritikhine
Jan 25, 2007·Chemistry : a European Journal·Gonzalo GivajaJason B Love
Jan 19, 2008·Nature·Polly L ArnoldJason B Love
Jul 10, 2009·Chemical Communications : Chem Comm·Jason B Love
Dec 17, 2009·Journal of the American Chemical Society·Grégory NoctonMarinella Mazzanti
May 13, 2010·Journal of the American Chemical Society·Jessie L BrownTrevor W Hayton
Nov 26, 2010·Nature Chemistry·Polly L ArnoldJason B Love
Jan 20, 2011·Angewandte Chemie·Polly L ArnoldJason B Love
Apr 27, 2011·Journal of the American Chemical Society·James W LeelandJason B Love
Aug 17, 2011·Inorganic Chemistry·David D SchnaarsTrevor W Hayton
Sep 29, 2011·Angewandte Chemie·Polly L ArnoldJason B Love
Dec 3, 2011·Chemical Communications : Chem Comm·Victor MougelMarinella Mazzanti
Mar 10, 2012·Science·Peter C BurnsAlexandra Navrotsky
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Jun 14, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Roy CoppingMarinella Mazzanti

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Citations

May 18, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Sokratis T TsantisSpyros P Perlepes
Jun 30, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Nicola L BellJason B Love
Jan 18, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Lucile ChatelainMarinella Mazzanti
Mar 29, 2018·Chemical Communications : Chem Comm·Bradley E CowiePolly L Arnold
Sep 22, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Pierre Thuéry, Jack Harrowfield
Jan 19, 2020·International Journal of Molecular Sciences·Sokratis T TsantisSpyros P Perlepes
Jun 5, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael A BoreenJohn Arnold
Sep 30, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Stephan HohlochJohn Arnold
Feb 19, 2021·Physical Chemistry Chemical Physics : PCCP·Luke J MetzlerMichael J Van Stipdonk
May 15, 2021·Physical Chemistry Chemical Physics : PCCP·Michael J Van StipdonkArpad Somogyi
Aug 14, 2021·Journal of the American Chemical Society·Fabrizio OrtuLouise S Natrajan
Jan 14, 2020·Journal of the American Chemical Society·Amit KumarJames D Blakemore
Dec 22, 2021·Chemical Communications : Chem Comm·Dennis GrödlerAida Raauf

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