Catalytic reactions involving the cleavage of carbon-cyano and carbon-carbon triple bonds

Chemical Society Reviews
Mamoru Tobisu, Naoto Chatani

Abstract

The catalytic reactions that involve the cleavage of C-CN bonds and carbon-carbon triple bonds are described in this tutorial review. Regarding the cleavage of a C-CN bond, the catalytic reaction can proceed by two different mechanisms: oxidative addition and deinsertion of silyl isocyanide. A carbon-carbon triple bond can be cleaved in the absence of an organic promoter via the formation of unique organometallic species, such as allenylidene and cyclopropyl carbenoid complexes.

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Citations

Jun 21, 2008·Chemical Communications : Chem Comm·Kazusa Ota, Naoto Chatani
Feb 28, 2014·The Journal of Organic Chemistry·Takanori Matsuda, Yusuke Sakurai
Dec 18, 2013·Journal of the American Chemical Society·Lina DingKeiji Morokuma
Apr 12, 2014·Journal of the American Chemical Society·Naoki IshidaMasahiro Murakami
Aug 19, 2014·Journal of the American Chemical Society·Zhaofeng WangYong Huang
Aug 15, 2014·The Journal of Organic Chemistry·Lijun GuLizhu Zhang
Mar 23, 2011·Organic Letters·Naveen R RondlaChristopher J Douglas
Jun 2, 2012·Organic Letters·Naoki IshidaMasahiro Murakami
Jan 22, 2013·Organic & Biomolecular Chemistry·Johannes E M N Klein, Bernd Plietker
Jan 29, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Andrew L JohnsonRaj Odedra
Feb 10, 2009·Journal of the American Chemical Society·Itaru NakamuraMasahiro Terada
Aug 31, 2012·Chemical Communications : Chem Comm·Shaoxia LinFushun Liang
Oct 24, 2012·Chemical Communications : Chem Comm·Mamoru TobisuNaoto Chatani
Feb 18, 2016·Angewandte Chemie·Pei Chui TooShunsuke Chiba
Dec 25, 2015·Chemical Communications : Chem Comm·Ran MaQing-Wen Song
Oct 8, 2009·Chemistry : a European Journal·Li-Zi YangTong-Bu Lu
Nov 14, 2015·Organic & Biomolecular Chemistry·Atanu Modak, Debabrata Maiti
Nov 28, 2008·Angewandte Chemie·Sergio M BonesiAngelo Albini
May 23, 2008·Angewandte Chemie·Mamoru TobisuNaoto Chatani
Jun 28, 2013·Angewandte Chemie·Chong QinNing Jiao
Oct 23, 2010·Chemistry : a European Journal·Sergio M Bonesi, Maurizio Fagnoni

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