PMID: 12778722Jun 5, 2003Paper

Cationic benzyl zirconium heteroscorpionates: synthesis and characterization of a novel ethylene polymerisation catalyst showing an unusual temperature dependent polymerisation mechanism

Chemical Communications : Chem Comm
Stefano MilioneAlfonso Grassi

Abstract

The reaction of (bpzmp)Zr(CH2Ph)3 with B(C6F5)3 produces the active ethylene polymerisation catalyst [(bpzmp)Zr(CH2Ph)2]+[PhCH2B(C6F5)3]- which showed a temperature dependent polymerisation mechanism identified by variable temperature 1H NMR analysis of the catalyst solution.

Citations

Dec 7, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Alberto Sánchez-MéndezPilar Gómez-Sal
Oct 15, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Zofia JanasKrzysztof Szczegot
Apr 1, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexander F R KilpatrickPhilip Mountford
Dec 17, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·A Daniel SchofieldPhilip Mountford
Sep 18, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Serhii TretiakovMarc-Etienne Moret
Jul 15, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·A OteroA Lara-Sánchez
Jan 13, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Antonio OteroIsabel López-Solera
Jun 29, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Maura PelleiCarlo Santini

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