Cationic magnesium hydride [MgH]+ stabilized by an NNNN-type macrocycle

Chemical Communications : Chem Comm
Lara E LemmerzJun Okuda

Abstract

A magnesium hydride cation [(L)MgH]+ supported by a macrocyclic ligand (L = Me4TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH2Mg{N(SiMe3)2}2] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.

References

Jul 18, 2002·Chemical Communications : Chem Comm·Daniel J GallagherRené B Rowlings
Apr 17, 2007·Inorganic Chemistry·Grigorii L SoloveichikEmil B Lobkovsky
Oct 18, 2008·Angewandte Chemie·Shaun P GreenAndreas Stasch
May 1, 2009·Angewandte Chemie·Merle ArrowsmithMary F Mahon
Oct 21, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael S HillMary F Mahon
Apr 8, 2011·Angewandte Chemie·Sjoerd HarderHeinz Bandmann
Apr 5, 2012·Chemical Communications : Chem Comm·Merle ArrowsmithGabriele Kociok-Köhn
Nov 8, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Richard A CollinsPhilip Mountford
Jan 12, 2013·Chemistry : a European Journal·Merle ArrowsmithGabriele Kociok-Köhn
Jun 25, 2013·Angewandte Chemie·Waldemar FeglerJun Okuda
May 16, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Sjoerd HarderJulia Intemann
Jul 22, 2014·Chemistry : a European Journal·David J LiptrotMary F Mahon
Jul 3, 2015·Chemistry : a European Journal·Silvia SchnitzlerJun Okuda
Jul 30, 2015·Angewandte Chemie·Mathew D AnkerMary F Mahon
Aug 19, 2015·Chemical Communications : Chem Comm·Catherine WeetmanMary F Mahon
Aug 27, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Yangyang SunJincai Wu
Sep 12, 2015·Chemical Communications : Chem Comm·Matthew E RobinsonIan Manners
Apr 14, 2016·Chemistry : a European Journal·Catherine WeetmanMary F Mahon
Jun 9, 2016·Chemistry : a European Journal·Lea Fohlmeister, Andreas Stasch
Oct 25, 2016·Chemistry : a European Journal·Jens LangerSjoerd Harder
Jan 26, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·S SchnitzlerJ Okuda
Apr 4, 2017·Angewandte Chemie·Jens LangerSjoerd Harder
Jun 24, 2017·Journal of the American Chemical Society·Mathew D AnkerLaurent Maron
Sep 5, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·I E Nifant'evP V Ivchenko
Nov 12, 2017·Angewandte Chemie·Debabrata Mukherjee, Jun Okuda
Jan 1, 2016·Chemical Science·Catherine WeetmanMary F Mahon
Aug 8, 2018·Nature Communications·Simon J BonyhadyCameron Jones
Oct 16, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Christoph StuhlReiner Anwander

❮ Previous
Next ❯

Citations

Nov 30, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Xianghui ShiJianhua Cheng
Jan 7, 2020·Chemical Communications : Chem Comm·Vladislav VasilenkoLutz H Gade
Jan 17, 2020·Chemistry : a European Journal·Danny SchuhknechtJun Okuda
Nov 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Lucas A FreemanRobert J Gilliard
Aug 9, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Clare Bakewell
Jan 19, 2021·Chemical Communications : Chem Comm·Caspar N de Bruin-DickasonCameron Jones
Jun 17, 2020·Inorganic Chemistry·Danny SchuhknechtJun Okuda
Aug 28, 2021·Chemical Reviews·Matthew M D RoyEric Rivard

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray
NMR

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.