CF3 SO2 X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3 SO2 Na

Beilstein Journal of Organic Chemistry
Hélène GuyonDominique Cahard

Abstract

Sodium trifluoromethanesulfinate, CF3SO2Na, and trifluoromethanesulfonyl chloride, CF3SO2Cl, are two popular reagents that are widely used for the direct trifluoromethylation of a large range of substrates. Further, these two reagents are employed for the direct trifluoromethylsulfenylation and trifluoromethylsulfinylation, the introduction of the SCF3 and the S(O)CF3 group, respectively. In addition to the aforementioned reactions, the versatility of these two reagents is presented in other reactions such as sulfonylation and chlorination. This first part is dedicated to sodium trifluoromethanesulfinate.

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Citations

Sep 1, 2018·Organic & Biomolecular Chemistry·Maojian LuShunyou Cai
Mar 22, 2019·Organic & Biomolecular Chemistry·Wolfgang JudDavid Cantillo
Jul 2, 2019·Chemical Communications : Chem Comm·Shuaishuai LiangWenbin Yi
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Mar 12, 2019·European Journal of Organic Chemistry·Jakob PletzWolfgang Kroutil
Oct 22, 2020·Chemical Communications : Chem Comm·Chun ZhangJie Wu
May 11, 2021·Chemical Communications : Chem Comm·Arun D KultheSrirama Murthy Akondi
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Mar 1, 2019·The Journal of Organic Chemistry·Yanyan YangMinjie Guo
Jun 28, 2019·The Journal of Organic Chemistry·Palasetty ChanduDevarajulu Sureshkumar
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Methods Mentioned

BETA
X-ray
NMR
electron paramagnetic resonance

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