Characterization of a palladium dihydrogen complex

Angewandte Chemie
Samantha J ConnellyD Michael Heinekey

Abstract

The preparation and isolation of the first palladium dihydrogen complex is described. NMR spectroscopy reveals a very short H-H bond length, but the hydrogen molecule is activated toward heterolytic cleavage. An X-ray crystal structure suggests that proton transfer to the (tBu) PCP (κ(3)-2,6-((t)Bu2PCH2)2C6H3) pincer ligand is possible. The basicity of the ipso-carbon atom of the pincer ligand was investigated in a related complex.

References

Mar 18, 2004·Chemical Society Reviews·D Michael HeinekeyJosé M Lluch
Jul 15, 2004·Journal of the American Chemical Society·Ricard GelabertD Michael Heinekey
Dec 21, 2006·Journal of the American Chemical Society·Inigo Göttker-SchnetmannMaurice Brookhart
Nov 18, 2009·Chemistry : a European Journal·Michael MontagDavid Milstein
Jan 2, 2010·Journal of the American Chemical Society·Tao HeKenneth G Caulton
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Lauren C GregorOleg V Ozerov
Feb 18, 2011·Angewandte Chemie·Travis J HebdenD Michael Heinekey
Mar 25, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Sanaa MusaDmitri Gelman
Sep 22, 2011·Journal of the American Chemical Society·Gregory R FulmerKaren I Goldberg
Mar 1, 2012·Inorganic Chemistry·Michael FindlaterMaurice Brookhart
Mar 8, 2012·Journal of the American Chemical Society·Paul KelleyTheodor Agapie
Aug 2, 2012·Inorganic Chemistry·Oana R LucaRobert H Crabtree
Aug 16, 2012·Journal of the American Chemical Society·Daniel L M SuessJonas C Peters
Nov 10, 2012·Chemistry : a European Journal·Samantha J ConnellyD Michael Heinekey
Dec 11, 2013·Angewandte Chemie·W Hill HarmanJonas C Peters

❮ Previous
Next ❯

Citations

Mar 15, 2016·Chemical Reviews·Robert H Crabtree
May 19, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Nicholas R WiedmaierLars Wesemann

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Chemistry : a European Journal
Samantha J ConnellyD Michael Heinekey
Angewandte Chemie
Travis J HebdenD Michael Heinekey
Journal of the American Chemical Society
Gregory C Welch, Douglas W Stephan
Chemical Reviews
Nicklas Selander, Kálmán J Szabó
© 2021 Meta ULC. All rights reserved