Characterizing the dark state in thymine and uracil by double resonant spectroscopy and quantum computation

Physical Chemistry Chemical Physics : PCCP
M LigareMattanjah S de Vries

Abstract

We report on gas phase double resonant spectroscopy of both the ground state and the dark excited state in isolated uracil and thymine. We also report lifetimes of the dark state for different excitation wavelengths. In combination with ab initio calculations the results suggest that the dark state is of triplet ((3)ππ*) character.

References

Jun 23, 1976·Journal of the American Chemical Society·D DoughertyS P McGlynn
Jun 13, 2002·Journal of the American Chemical Society·Nina IsmailMichael A Robb
Oct 31, 2002·Journal of the American Chemical Society·Hyuk KangSeong Keun Kim
Jan 11, 2005·The Journal of Chemical Physics·Vincenzo Barone
Mar 4, 2005·The Journal of Chemical Physics·Clélia CanuelMohamed Elhanine
Apr 28, 2005·Journal of the American Chemical Society·Serhiy PerunWolfgang Domcke
May 6, 2006·The Journal of Chemical Physics·Hui Chen, Shuhua Li
May 30, 2006·Proceedings of the National Academy of Sciences of the United States of America·Luis Serrano-AndrésAntonio C Borin
Jul 27, 2006·The Journal of Physical Chemistry. a·Marek Z ZgierskiEdward C Lim
Dec 8, 2006·The Journal of Physical Chemistry. a·Serhiy PerunWolfgang Domcke
Jan 2, 2007·Proceedings of the National Academy of Sciences of the United States of America·Patrick M HareBern Kohler
Feb 6, 2007·The Journal of Physical Chemistry. a·Christel M Marian
Apr 19, 2007·The Journal of Physical Chemistry. a·Vanesa VaqueroJosé L Alonso
May 26, 2007·The Journal of Chemical Physics·Juan C LópezJosé L Alonso
Aug 10, 2007·The Journal of Physical Chemistry. a·Hanneli R HudockTodd J Martínez
Oct 12, 2007·The Journal of Physical Chemistry. B·Juan José Serrano-PérezLuis Serrano-Andrés
Jan 25, 2008·Journal of the American Chemical Society·Luis Serrano-AndrésAntonio Carlos Borin
May 1, 2008·Journal of the American Chemical Society·Mario Barbatti, Hans Lischka
Jun 10, 2008·The Journal of Chemical Physics·Kurt A Kistler, Spiridoula Matsika
Jul 10, 2008·The Journal of Physical Chemistry. a·E Fabiano, W Thiel
Jul 12, 2008·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Matthias BuskerTimo Fleig
Sep 6, 2008·The Journal of Physical Chemistry. a·Evgeny EpifanovskyAnna I Krylov
Apr 28, 2009·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Zhenggang LanWalter Thiel
May 15, 2009·Physical Chemistry Chemical Physics : PCCP·Jesús González-VázquezThomas Schultz
Aug 13, 2009·The Journal of Physical Chemistry. a·Mihajlo EtinskiChristel M Marian
Aug 21, 2009·The Journal of Physical Chemistry. a·Jaroslaw J SzymczakHans Lischka
Sep 30, 2010·Physical Chemistry Chemical Physics : PCCP·Juan Carlos LópezVanesa Vaquero
Dec 1, 2010·Proceedings of the National Academy of Sciences of the United States of America·Mario BarbattiHans Lischka
Jan 12, 2011·The Journal of Chemical Physics·Mario BarbattiHans Lischka
Feb 25, 2011·Physical Chemistry Chemical Physics : PCCP·Mario BarbattiHans Lischka
Apr 8, 2011·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Maksim KunitskiBernhard Brutschy
May 10, 2011·The Journal of Physical Chemistry. a·Dana NachtigallováHans Lischka

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Citations

Aug 20, 2016·Physical Chemistry Chemical Physics : PCCP·Ashley A BecksteadBern Kohler
Sep 23, 2016·The Journal of Physical Chemistry Letters·Kaoru YamazakiTakayuki Ebata
Nov 26, 2016·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Ljiljana StojanovićMario Barbatti
Apr 6, 2018·Physical Chemistry Chemical Physics : PCCP·Samuel Boldissar, Mattanjah S de Vries
May 1, 2021·The Journal of Physical Chemistry Letters·Woojin ParkCheol Ho Choi
May 12, 2018·The Journal of Physical Chemistry. a·Bert M PillesWolfgang J Schreier

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