Chiral [MnII MnIII3 M'] (M'=NaI , CaII , MnII ) and [MnII MnIII6 NaI2 ] Clusters Built from an Enantiomerically Pure Schiff Base: Synthetic, Chiroptical, and Magnetic Properties

Chemistry : a European Journal
Julia MayansAlbert Escuer

Abstract

From the reaction of manganese halides with the chiral Schiff bases obtained by condensation of o-vanillin and (R)- or (S)-phenylglycinol, 11 complexes based on pentanuclear cages with trigonal bipyramidal [MnII MnIII3 M'] (M'=NaI , CaII , MnII ) or enneanuclear [MnII MnIII6 NaI2 ] cores were synthesized. Structural, supramolecular chirality, and optical properties were explored. The magnetic properties of related systems were reviewed, and the magnetic response of the new systems was rationalized to the bond parameters.

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Citations

Mar 20, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Júlia MayansAlbert Escuer
Oct 12, 2018·Clinical Toxicology : the Official Journal of the American Academy of Clinical Toxicology and European Association of Poisons Centres and Clinical Toxicologists·Lotte Christine Groth HoegbergAnita Annas
Jul 23, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Thomais G TziotziConstantinos J Milios

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