Circular dichroism in the photoelectron angular distributions of camphor and fenchone from multiphoton ionization with femtosecond laser pulses

Angewandte Chemie
Christian LuxThomas Baumert

Abstract

Shine a light: a circular dichroism effect in the ±10 % regime on randomly oriented chiral molecules in the gas phase is demonstrated. The signal is derived from images of photoelectron angular distributions produced by resonance-enhanced multiphoton ionization and allows the enantiomers to be distinguished. To date, this effect could only be generated with a synchrotron source. The new tabletop laser-based approach will make this approach far more accessible.

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Citations

Feb 23, 2013·Analytical and Bioanalytical Chemistry·Ulrich BoeslKatharina Titze
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