Clicked Isoreticular Metal-Organic Frameworks and Their High Performance in the Selective Capture and Separation of Large Organic Molecules

Angewandte Chemie
Pei-Zhou LiYanli Zhao

Abstract

Three highly porous metal-organic frameworks (MOFs) with a uniform rht-type topological network but hierarchical pores were successfully constructed by the assembly of triazole-containing dendritic hexacarboxylate ligands with Zn(II) ions. These transparent MOF crystals present gradually increasing pore sizes upon extension of the length of the organic backbone, as clearly identified by structural analysis and gas-adsorption experiments. The inherent accessibility of the pores to large molecules endows these materials with unique properties for the uptake of large guest molecules. The visible selective adsorption of dye molecules makes these MOFs highly promising porous materials for pore-size-dependent large-molecule capture and separation.

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Citations

May 10, 2017·Chemical Communications : Chem Comm·Fangna DaiDaofeng Sun
Mar 11, 2017·Chemical Communications : Chem Comm·Pei-Zhou LiYanli Zhao
Dec 2, 2017·Chemistry : a European Journal·Peng JingPeng Cheng
Dec 21, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Lin LuoHao-Ling Sun
Oct 13, 2018·Chemical Communications : Chem Comm·Daeok KimAli Coskun
Apr 5, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Pan HuangMaochun Hong
Dec 10, 2019·Angewandte Chemie
Jun 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jing AiZhong-Ming Sun
Apr 24, 2020·Nanoscale Horizons : the Home for Rapid Reports of Exceptional Significance in Nanoscience and Nanotechnolgy·Heba AhmedLeslie Y Yeo
Feb 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Bhavesh ParmarEringathodi Suresh
Mar 2, 2021·ACS Applied Materials & Interfaces·Benson Peter MugakaXing-Hua Xia
Aug 10, 2018·Journal of the American Chemical Society·Dengke ShenJ Fraser Stoddart
Oct 27, 2017·Journal of the American Chemical Society·Jiandong PangMaochun Hong
Jul 13, 2019·Journal of the American Chemical Society·Yujuan ZhouFeihe Huang

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