CO2: a wild solvent, tamed

Physical Chemistry Chemical Physics : PCCP
Stephen CummingsJulian Eastoe

Abstract

This article reviews approaches for modification of solvent properties of supercritical carbon dioxide (scCO(2)), with particular reference to self-assembly of oligomeric and polymeric solute additives. Of special interest are viscosity modifiers for scCO(2) based on molecular self-assembly. Background on polymers and surfactants with CO(2)-compatible functionalities is covered, leading on to the attempts made so far to increase the scCO(2) viscosity, which are described in detail. The significance of this field, and the implications a breakthrough could bring environmentally and economically will be addressed.

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Citations

Dec 25, 2013·Langmuir : the ACS Journal of Surfaces and Colloids·Craig JamesJulian Eastoe
May 23, 2014·Journal of Molecular Modeling·Chang HonghongQiao Yan
May 19, 2012·Physical Chemistry Chemical Physics : PCCP·Khashayar GhandiMarisa Smith
Jan 20, 2016·Journal of Molecular Modeling·H H ChangY Qiao
Mar 19, 2013·Journal of Colloid and Interface Science·Audrey FavrelleAntoine Debuigne
Jul 13, 2011·Biochimie·Stephen CummingsJulian Eastoe
Sep 24, 2014·Beilstein Journal of Organic Chemistry·Jocelyn Peach, Julian Eastoe
Sep 26, 2012·Physical Review Letters·Zhiping WangYuxiang Bu
Dec 11, 2020·Langmuir : the ACS Journal of Surfaces and Colloids·Yingnan ZhangMuhan Wang

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