CO2 Binding and Splitting by Boron-Boron Multiple Bonds

Angewandte Chemie
Andreas StoyHolger Braunschweig

Abstract

The room-temperature, ambient-pressure reactions of CO2 with two species containing boron-boron multiple bonds led to the incorporation of either one or two CO2 molecules. The structural characterization of a thermally unstable intermediate in one case indicates that an initial [2+2] cycloaddition is the key step in the reaction mechanism.

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Oct 16, 2018·Angewandte Chemie·Esther von GrotthussMatthias Wagner
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