PMID: 26346380DOI: 10.1039/c5cc06707cSep 9, 2015Paper
CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex
Chemical Communications : Chem Comm
Clément CampMarinella Mazzanti
Abstract
The reaction of the sterically saturated uranium(III) tetrasilylamido complex [K(18c6)][U(N(SiMe3)2)4] with CO2 leads to CO2 insertion into the U-N bond affording the stable U(IV) isocyanate complex [K(18c6)][U(N(SiMe3)2)3(NCO)2]n that was crystallographically characterized. DFT studies indicate that the reaction involves the [2+2] cyclo-addition of a double bond of O=CO to the U-N(SiMe3)2 bond and proceeds to the final product through multiple silyl migration steps.
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Citations
Sep 7, 2016·Inorganic Chemistry·Danil E SmilesTrevor W Hayton
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May 29, 2020·Inorganic Chemistry·Michael A BoreenJohn Arnold
May 30, 2020·Inorganic Chemistry·Raza Ullah Shah BachaQing-Jiang Pan
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