Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

Dalton Transactions : an International Journal of Inorganic Chemistry
Justin K PaganoRory Waterman

Abstract

Two cobalt compounds, Cp*Co(CO)I2 (1) and CpCo(CO)I2 (2) (Cp* = η(5)-C5Me5, Cp = η(5)-C5H5), catalyze the dehydrogenation of ammonia borane under either anaerobic or aerobic conditions and are also effective hydrogenation catalysts for alkenes and alkynes using ammonia borane as a hydrogen source, also in the presence of air.

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Citations

Dec 19, 2016·Chemical Communications : Chem Comm·Eva KorytiakováJohannes F Teichert
Mar 17, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yong WuXingguo Li
Aug 30, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·M TroseT Beweries
Nov 1, 2018·Chemistry : a European Journal·Thomas M MaierRobert Wolf
May 8, 2019·Angewandte Chemie·Michael DömlingHolger Braunschweig
Dec 13, 2019·Chemical Communications : Chem Comm·Timothy M BoydAndrew S Weller
Sep 26, 2020·Organic & Biomolecular Chemistry·Chiara FaverioMaurizio Benaglia
Dec 7, 2018·Journal of the American Chemical Society·Maialen Espinal-ViguriRuth L Webster
Oct 15, 2021·Inorganic Chemistry·Adam N BarrettRuth L Webster

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