Complexation of asymmetric diborenes with magnesium bromide

Chemical Communications : Chem Comm
Wei Lu, Rei Kinjo

Abstract

The synthesis of neutral Mg complexes of asymmetric diborenes is reported. X-ray diffraction analysis reveals that the Mg center is unsymmetrically coordinated to the B2 units of diborenes. Theoretical calculations manifest the donation of electrons from the π-type orbitals of diborenes to an empty orbital of Mg.

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Citations

Mar 29, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Atsumi YagiMakoto Yamashita
Jul 3, 2019·Angewandte Chemie·Seiji AkiyamaMakoto Yamashita
Mar 22, 2019·Journal of the American Chemical Society·Wei LuRei Kinjo

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Methods Mentioned

BETA
NMR
X-ray

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